the difference is the 'countries' that are listed in the catalog. the Collecting Coins eliminates many of the coin issuing entities that don't really have circulation coinage. Examples of World Catalog 'countries' not listed in Collecting Coins
Ajman, Alderney, American Samoa, Antigua and Barbuda, Belarus. I would guess the differences changes from edition to edition but I did a quick comparison of the 2009 versions of each to get these












