Carbon spots are from something being on the cent prior to storage. The album didn't do it nor could it prevent it from happening. Like a finger print it is etched into the copper over time. While you might be able to tone it down and stop it from getting worse, the damage is done.
The 1960 seller doctors cents. It does look like a removed spot. Look at his wheat cents and you'll see they are the same color. What are the odds?











