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Cleaning Verdigris From Silver Coins. One Technique

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Valued Member
Australia
295 Posts
 Posted 03/10/2014  11:57 am  Show Profile   Bookmark this reply Add awildeheart to your friends list
Well Bad Thad, it would be nice to have access to VerdiCare in Australia ... but unfortunately not all newbie/low budget coin collectors live in the USA.

When postage (JUST postage, not for the actual product itself) is more than $24 to mail a small 60ml bottle here via your ebay store ... VerdiCare suddenly does not seem a viable solution for collectible-but-not-expensive coins that have a small amount of verdigris.

If this process gently stops verdigris on a coin that would otherwise be worthless as the verdigris progresses, then it seems a chance worth taking in my books.
Pillar of the Community
United States
1666 Posts
 Posted 03/10/2014  9:47 pm  Show Profile   Bookmark this reply Add Numismat to your friends list
This seems like a more complicated process than just using diluted acetone and xylene to achieve the same effect. And honestly I think that coin looks worse in the after picture than the before picture.
Edited by Numismat
03/10/2014 9:48 pm
Pillar of the Community
2087 Posts
 Posted 03/11/2014  01:49 am  Show Profile   Bookmark this reply Add austrokiwi to your friends list

Quote:
This seems like a more complicated process than just using diluted acetone and xylene to achieve the same effect. And honestly I think that coin looks worse in the after picture than the before picture.


In real life it actually looks heaps better. If you have some tarnished silver try it on that ( not anything with stones or pearls on it) Actually the reaction is very fast sometimes taking less than 30 seconds. I will try to post a better photo later to day
Bedrock of the Community
United States
19972 Posts
 Posted 03/12/2014  08:34 am  Show Profile   Bookmark this reply Add BadThad to your friends list

Quote:
Well Bad Thad, it would be nice to have access to VerdiCare in Australia ... but unfortunately not all newbie/low budget coin collectors live in the USA.

When postage (JUST postage, not for the actual product itself) is more than $24 to mail a small 60ml bottle here via your ebay store ... VerdiCare suddenly does not seem a viable solution for collectible-but-not-expensive coins that have a small amount of verdigris.


Are you blaming me for you living on the other side of the planet?
Lincoln Cent Lover!
VERDI-CARE™ INVENTOR
https://verdi.care/
Bedrock of the Community
United States
19972 Posts
 Posted 03/12/2014  08:35 am  Show Profile   Bookmark this reply Add BadThad to your friends list

Quote:
This seems like a more complicated process than just using diluted acetone and xylene to achieve the same effect. And honestly I think that coin looks worse in the after picture than the before picture.


Verdigris is INSOLUBLE in organic solvents. The primary constituents in verdigris are inorganic salts.
Lincoln Cent Lover!
VERDI-CARE™ INVENTOR
https://verdi.care/
Valued Member
Australia
295 Posts
 Posted 03/12/2014  10:35 am  Show Profile   Bookmark this reply Add awildeheart to your friends list

Quote:
Are you blaming me for you living on the other side of the planet?


No Bad Thad, but I am blaming you for over-charging way too much for postage. I buy a lot of stuff on the internet from all over the world and rarely pay postage. And the few times I do, it is at a reasonable cost and I don't mind paying it.

BUT paying over $24 postage for a small 60ml bottle of stuff is highway robbery. When I queried it with you, your 'solution' was to recommend I buy double of your product to make the postage costs worthwhile. Not very good customer service relations to suggest an already upset customer doubles their order (doubling the profit to you) to make the most of your inflated shipping costs.

And before you say you have a third party handling the shipping and it is out of your hands, maybe you need to look at finding cheaper shipping options to allow the Aussie coinaholics to purchase your product and spread the VerdiCare love?
Edited by awildeheart
03/12/2014 12:55 pm
Bedrock of the Community
United States
17884 Posts
 Posted 03/12/2014  12:13 pm  Show Profile   Bookmark this reply Add Conder101 to your friends list
The posted procedure will remove tarnish, it will not remove verdigris. It is also pretty much the same as usign a commercial dip. It strips the surface, but uses a base solution instead of an acid one. Either way it causes the same surface damage to the coin and if overdone will strip the luster. Bases can be just as corrosive as acids.
Bedrock of the Community
United States
19972 Posts
 Posted 03/13/2014  1:41 pm  Show Profile   Bookmark this reply Add BadThad to your friends list

Quote:
BUT paying over $24 postage for a small 60ml bottle of stuff is highway robbery. When I queried it with you, your 'solution' was to recommend I buy double of your product to make the postage costs worthwhile. Not very good customer service relations to suggest an already upset customer doubles their order (doubling the profit to you) to make the most of your inflated shipping costs


Well, contact USPS and ebay. I offer FREE shipping, they set the prices. I make ZERO DOLLARS from shipping!

Lincoln Cent Lover!
VERDI-CARE™ INVENTOR
https://verdi.care/
Edited by BadThad
03/13/2014 1:43 pm
Pillar of the Community
2087 Posts
 Posted 03/14/2014  10:06 am  Show Profile   Bookmark this reply Add austrokiwi to your friends list

Quote:
The posted procedure will remove tarnish, it will not remove verdigris. It is also pretty much the same as usign a commercial dip. It strips the surface, but uses a base solution instead of an acid one. Either way it causes the same surface damage to the coin and if overdone will strip the luster. Bases can be just as corrosive as acids


WRONG! First6 off it is completely different to a dip, Its a sacrificial metal process. Similar to that used to prevent corrosion on Oil rigs(Magnesium blocks) Its an electro-chemical process(like a battery). The coin I posted now has a copper sheen where the verdigris was. The soda only acts as an electrolyte. When the coin touches the the foil some of the foil is corroded while the corrosion on the coin is reversed) this includes the verdigris....Obviously there's some people here who have a commercial interest in putting people off this process. They want to make people use their product rather than something cheaper.Accordingly they are naturally biased against anything that challenges their profits. As I said at the out set I only recommended it for already damaged coins...and look how threatened BadThad was over that!!

Its amazing how commercial interests will rubbish something and misconstrue what it does so as to support their products.

Here is one of the chemical formula's that explains how the silver sulfides are affected in this process( I don't have the formula for the copper compounds in verdigris but copper sulphate is a significant component of verdigris):


3 Ag2S + 2 Al --/> 6 Ag + Al2S3
silver
sulfide aluminum silver aluminium sulfide


Actually I found another name for the process Electrolytic cleaning:

See this entry in Wikipedia and scroll down to Electrolytic cleaning don't be scared of the term "Galvanic corrosion" in this process it is the Aluminium foil that is being corroded

I would suggest the verdi care people stop pushing on this one because some of the research I have done to check how the aluminium foil actually works suggests there are some very real concerns about verdicare Such as: As you remove the verdigris you must be removing some of the coins original metal.
Edited by austrokiwi
03/14/2014 10:51 am
Moderator
Learn More...
United States
23522 Posts
 Posted 03/14/2014  5:41 pm  Show Profile   Bookmark this reply Add SsuperDdave to your friends list

Quote:
Actually I found another name for the process Electrolytic cleaning:


So, you've just now "discovered" electrolytic cleaning, and all of a sudden you're an expert chemist and coin conservationist?

Forgive me, austrokiwi, but

A correct-but-incomplete understanding is just as wrong as being completely in the dark.
New Member
United States
25 Posts
 Posted 03/15/2014  09:10 am  Show Profile   Bookmark this reply Add dei gratia regina to your friends list

Quote:
BUT paying over $24 postage for a small 60ml bottle of stuff is highway robbery.


You going to yell at the maker of the 2x2's for the distributor's high shipping, too?

There have a couple posts by people offering to ship it to members overseas, one by a mod if I remember correctly. Take them up on it if you want to. You lashing out at a manufacturer because of the distributor's policies/ship charge is just plain ignorant.

Regarding the foil 'technique' - while it's great for tarnished silver, what you aren't realizing - or at the least did not state - is that the process takes a bit of the silver with it when it moves to the foil. Your first sentence needs to be bolded and enlarged: This is a chemical process and should only be used, IMHO, for gap fillers where you wish to prevent further deteriation and stabilise the coin. It's a harsher method than a dip. It sounds like you're very new to it, so I'd suggest you proceed with a great deal of caution if you're going to keep doing this to coins.


Quote:
Obviously there's some people here who have a commercial interest in putting people off this process.

Yes. We like our coins undamaged. Sooner or later the ones being killed of any numismatic value in this manner are going to leave your hands, and in the same manner that caution is urged against any other harsh method, other people will warn against it. So yes, I believe many have a commercial interest.
Valued Member
Australia
295 Posts
 Posted 03/15/2014  09:15 am  Show Profile   Bookmark this reply Add awildeheart to your friends list
SsuperDdave, I'm really surprised a moderator would be so insulting to a forum member.

Bad Thad, your attitude is equally insulting and very surprising for both a business man and a forum member with nearly 11,000 posts on this forum.

This is my last contribution to this public thread, but if you would like to continue the conversation privately then by all means email me.

My last public point addresses Bad Thad's response of
Quote:
Well, contact USPS and ebay.
which totally ignored the point in my prior suggestion of:


Quote:
And before you say you have a third party handling the shipping and it is out of your hands, maybe you need to look at finding cheaper shipping options to allow the Aussie coinaholics to purchase your product and spread the VerdiCare love?


I checked the USPS website and found this much more reasonable postage rate, so why are you charging over $24AUD?:

Cleaning-Verdigris-From-Silver-Coins.-One-Technique
Valued Member
Australia
295 Posts
 Posted 03/15/2014  09:28 am  Show Profile   Bookmark this reply Add awildeheart to your friends list
... was going to be my last public post on this thread except for the comment posted by dei gratia regina eight minutes ago while I was writing that posting.


Quote:
You lashing out at a manufacturer because of the distributor's policies/ship charge is just plain ignorant.


No, it is not "just plain ignorant" of me, and again I am surprised at the insulting language being used.

I raised that point not through ignorance, but purely BECAUSE of my knowledge of the standard postage fees I have paid over the last ten years for many different sized items posted from many different countries. I have bought many items from America - and most have been much bigger and heavier items than a 2.2 ounce/60ml bottle - and have ONLY ever paid a reasonable price for postage.

Over $24AUD IS ridiculous and overpriced.
Pillar of the Community
United States
2669 Posts
 Posted 03/15/2014  11:45 am  Show Profile   Bookmark this reply Add xshift to your friends list
Perhaps I missed something - you said "via your ebay store" - Is that BadThad's ebay store?
Pillar of the Community
United States
2669 Posts
 Posted 03/15/2014  11:45 am  Show Profile   Bookmark this reply Add xshift to your friends list
And by the way, "ignorant" is not an insult. It means uninformed or having no knowledge of something.
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