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Acid Damaged Coin?

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SPP-Ottawa's Avatar
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 Posted 12/28/2014  8:41 pm  Show Profile   Check SPP-Ottawa's eBay Listings Bookmark this reply Add SPP-Ottawa to your friends list Get a Link to this Reply

Quote:
what kind / type of acid does produce this porous effect on both sides? AND, does it on copper and silver.


Did you even try to Google that question? The answers you seek are all available online, with basic chemistry questions.

MANY acids will dissolve bronze and Ag-Cu alloys. Nitric acid, sulphuric acid and hydrochloric acid. Or, a mixture of nitric and hydrochloric acid (aqua regia) can dissolve stainless steel, iron, nickel alloys as well. The stronger the acid, the more vigorous the attack.

1M (or stronger) HCL is used in a common experiment in high school chemistry classes, and within 3 minutes, can turn a normal bronze penny into a paper-thin wafer.

Why not try an experiment yourself, in a well-ventilated area, with battery acid?
"Discovery follows discovery, each both raising and answering questions, each ending a long search, and each providing the new instruments for a new search." -- J. Robert Oppenheimer

Content of this post is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported License. See: http://creativecommons.org/licenses...0/deed.en_US

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Sap's Avatar
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 Posted 12/28/2014  8:59 pm  Show Profile   Bookmark this reply Add Sap to your friends list Get a Link to this Reply

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wow.... is that for real? that coin was gone in NO time...

It's real, but time-lapsed - the reaction isn't that fast in real life.

As for 47P7's questions on acid reactions with coins, the end result does depend on several different factors.

Yes, a shiny coin dipped in acid (and I'm including "coca-cola" or other carbonated soft drinks in my definition of "acid") briefly then washed thoroughly straight away will look fairly smooth and non-porous once it's done, because the acid eats away at all the surfaces at the same rate.

Pitting occurs when there is something to cause different rates of reaction. A circulation-toned coin is a good example of something that can cause this; the oxide layer is unevenly thick. The video shows a good demonstration of how this oxide layer provides some initial protection against the acid, as the initial reaction is much slower than the later reaction.

Another excellent way to create a pitted coin is to not wash off the acid properly, but just let it dry there. The acid becomes stronger in some places than others, eating away those spots. I learned this to my cost as a YN after seeing a science show on TV telling me how to make my copper coins shiny using lemon juice; they forgot to say "make sure you wash the coin thoroughly afterwards".

Silver is a more "noble" metal than copper, which means that copper and copper alloys are much easier to eat away with acids than silver. Weaker acids like coke and vinegar simply do nothing visible to silver. You can't use any chloride-based acid like hydrochloric either, because that quickly forms a silver chloride layer that stops further corrosion. Nitric acid, however, does the job on silver nicely.

The presence of the distinctive brown fumes towards the end of the video indicates that the acid used here is nitric, or perhaps a mixture of nitric with something else. Aqua regia, an acid mixture which can famously dissolve gold, is a mixture of nitric and hydrochloric acids.

Quote:
BTW, the OP-link, coin is removed from the bay.

No it's not. I can still see it.

And it shows all the hallmarks of a classic acid-attacked coin. "This a paper thin coin" is perhaps the most telling sign of all. It certainly is not a mint error and is not worth the hundreds being asked for it.
Don't say "infinitely" when you mean "very"; otherwise, you'll have no word left when you want to talk about something really infinite. - C. S. Lewis
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47P7's Avatar
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 Posted 12/29/2014  04:28 am  Show Profile   Bookmark this reply Add 47P7 to your friends list Get a Link to this Reply
SPP,
where I went to school, there were NO chemistry classes. There were four teachers for 8 grades.
Class sizes were anywhere up to 20. School started by law at age 5 or 6, depending on your birthday. Period! Unfortunately I am not as lucky as some people who received the best schooling, education and endless degrees. Never mind high school or University.
My parents simply did not have the funds for that! I had to be happy to get a chance to become a Tradesman. I was given three choices at age 13: Mechanic, Electrician or to be a common worker for the rest of my life. I think you understand it was not all that easy.
I sincerely hope that you and everyone will try to understand why I ask questions when I do not know something! Or something does not makes sense or I do not understand it.
Why should one seek answers from Google for a forum topic when the answers are probably available from forum members?
I believe that is what the forum is here for as it has many knowledgeable members who are willing to answer questions if someone does not know what it is all about.
and guess what? if I do not understand an answer, or an answer is circumventing an issue , I will probably ask again. Now, what is wrong with that?

SAP
Thank you for having the interest and patience to address my questions in a simple to understand language.
I most certainly do understand a bit more now.
However, I will still not experiment with any of these dangerous components. Anything that goes past household bleach or brasso or similar is simply off limit for me.

I do have a few "attacked" and interesting looking coins and am wondering why someone would destroy a perfectly good coin with acid?
I can understand drilling a hole in it...

Yes, the listing is still there, but not active any more.
should have expressed that differently, sorry.
Edited by 47P7
12/29/2014 04:44 am
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Sap's Avatar
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 Posted 12/29/2014  04:59 am  Show Profile   Bookmark this reply Add Sap to your friends list Get a Link to this Reply

Quote:
I do have a few "attacked" and interesting looking coins and am wondering why someone would destroy a perfectly good coin with acid?

To quote from Star Trek IV, "Whoever said the human race was logical?"

As with any post-mint damage, some acid-attacked coins may have been made by accident. Car batteries contain concentrated sulfuric acid; an accident with a battery in a workshop or garage could easily see a pool of acid slowly flowing over a coin sitting on the floor, or down a drain that had earlier trapped a coin. Or a bottle of vinegar in the kitchen gets knocked over into the change jar. Or maybe a beach-combing metal detectorist decides to use acid to clean up their corroded finds to make them look more coin-like before spending them.

Others are simply human curiosity: the attitude of "I wonder what happens if I do this to this" has caused many serendipitous scientific discoveries and created many odd and curious artefacts down through the ages. Everyone thinks they're the first person to wonder what happens when a coin is dropped into cola. Or, in more modern times, they see a science-for-kids TV show or YouTube video and, wishing to test its veracity, decide to try to replicate the experiment themselves.

Some may have been made deliberately, for fraudulent purposes or otherwise. In some countries, counterfeiters might try turning a large low-denomination coin into a smaller, thinner but more valuable coin. Deceptive ebay sellers might offer them for sale to the gullible as "unique mint errors". Or maybe an artist wants to make a statement about the ephemerality of the monarchy.
Don't say "infinitely" when you mean "very"; otherwise, you'll have no word left when you want to talk about something really infinite. - C. S. Lewis
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Fixguy's Avatar
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 Posted 12/29/2014  09:31 am  Show Profile   Bookmark this reply Add Fixguy to your friends list Get a Link to this Reply
47P7 there's nothing wrong with questions. I've had a lot of them over the years and I'm no expert. I offer what I've found as information and I try and not flood the board. Everyone here has an interest much like yourself. Sometimes I get condescending comments to things I've posted and I find it sours me to collecting a bit. Regardless I've made a few solid friends here. I've purchased an acid coin in the past so I've resolved myself to never purchase anything that is questionable regarding corrosion or weight or thickness. Here's an interesting article I offer for reading: http://www.coingalaxy.com/coininfo/acid.html hope the hyper link is ok.
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SPP-Ottawa's Avatar
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 Posted 12/29/2014  10:17 am  Show Profile   Check SPP-Ottawa's eBay Listings Bookmark this reply Add SPP-Ottawa to your friends list Get a Link to this Reply

Quote:
Why should one seek answers from Google for a forum topic when the answers are probably available from forum members?


Because the forum here provides the "what" (that is, the short answer). You want to know if something is post mint damage, then the members will tell you in about as many words, based on their experience.

Google, will provide you with the "why" and "how" (the longer answers you seek).
"Discovery follows discovery, each both raising and answering questions, each ending a long search, and each providing the new instruments for a new search." -- J. Robert Oppenheimer

Content of this post is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported License. See: http://creativecommons.org/licenses...0/deed.en_US

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Pacificoin's Avatar
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 Posted 12/29/2014  11:03 am  Show Profile   Check Pacificoin's eBay Listings Bookmark this reply Add Pacificoin to your friends list Get a Link to this Reply
47 this forum is just part of the overall puzzle when trying to solve a numismatic equation. Google searches and other numismatic websites are to considered "your electronic library" and will only enhance your knowledge and abilities. SPP is right this forum is great but it is just a first step in a journey of many miles when it comes to numismatics.
I am not sure what your situation is when it comes to an actual numismatic library, ie how many books you have. But I can assure you that you can 500 or more as I do and that is still not enough.
For this subject at hand I can recommend the book "Coin Chemistry 3rd edition Weimar W. White ". In my opinion 500 dollars spent on books is better than 10K spent on coins.
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Alexer's Avatar
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 Posted 12/29/2014  11:25 am  Show Profile   Bookmark this reply Add Alexer to your friends list Get a Link to this Reply
@ 47p7
For anyone who doesn't want to handle these chemicals ( or is to young to do so ) its easier and safer to go to Google or Youtube to observe what different acids do. Playing with battery acid is not a good idea. The more acid coins you see the easier it becomes to determine just what it is your looking at. Searching the internet is just homework that we have all done now its your turn. All the ways different chemicals attack different metals..its to much to list.
Spend some time searching this and you too will say - "acid coin IMO"
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47P7's Avatar
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 Posted 12/29/2014  12:22 pm  Show Profile   Bookmark this reply Add 47P7 to your friends list Get a Link to this Reply
Thanks everyone for the education about acid coins. It does make sense what you guys say. And I guess for lack of "in depth" understanding of the workings and reactions of acid, I will simply have to accept what it does, I. e. the end result, and not needing to know or understand HOW it gets that result. That is ok.
next time, I promise, I will join the Chorus and suggest "acid coin".
Thanks again guys.
I will post a few images later today which at first sight look like acid coins, but most likely are not.
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SilverDon's Avatar
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 Posted 12/29/2014  8:46 pm  Show Profile   Bookmark this reply Add SilverDon to your friends list Get a Link to this Reply
People who ask questions are trying to enhance their understanding, not a bad thing.
Some forum members have the answers at hand, this is a good thing.
I believe in helping one's self, but again that is what a forum of like minds is for, an exchange of ideas.
The fact that there are those at different learning levels is going
to create an imbalance. Meet the question with a forthright and true
answer. Put your information forward without editorial. Offer the
inexperienced a hand, we may stop asking the questions if met with
opposition to a query. Not everyone has access to the libraries of
which you speak. Not everyone has an interest in the hobby to the extent that some would hope.
I can google with the best of them, I come here for
the personal attention to detail and to ask and have answered specific questions.
Is there a problem with this?
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Fixguy's Avatar
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532 Posts
 Posted 12/29/2014  9:39 pm  Show Profile   Bookmark this reply Add Fixguy to your friends list Get a Link to this Reply
Well said SilverDon.
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Pacificoin's Avatar
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 Posted 12/29/2014  9:48 pm  Show Profile   Check Pacificoin's eBay Listings Bookmark this reply Add Pacificoin to your friends list Get a Link to this Reply
Silver Don .. agree but I will say a couple of things. When you get the basic info from some stuff on this forum it can be great fun to further research the net or find stuff in a book sort of a like building a pyramid from the base up. Also my library of numismatic books is there for all to share. If I can possibly help anyone on this forum I will share to the best of my ability. Knowledge is the most powerful tool in numismatics and should be shared.
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Alexer's Avatar
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2632 Posts
 Posted 12/29/2014  10:09 pm  Show Profile   Bookmark this reply Add Alexer to your friends list Get a Link to this Reply

Quote:
The fact that there are those at different learning levels is going to create an imbalance


It creates the perfect balance actually, if we we're all the same level that would be an imbalance. IMO thats how we learn from one another.




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SilverDon's Avatar
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 Posted 12/29/2014  10:29 pm  Show Profile   Bookmark this reply Add SilverDon to your friends list Get a Link to this Reply
Pacificoin - I thank you for the offer of your numismatic library, I will take you up on that in the future. Cheers.

penneyman007 - I agree, a perfect balance is also a free flow of ideas, information sharing.

Fixguy - thanks.
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Vancouver IslandCoinKid's Avatar
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1074 Posts
 Posted 01/02/2015  10:00 pm  Show Profile   Bookmark this reply Add Vancouver IslandCoinKid to your friends list Get a Link to this Reply
Yes interesting when these come up!
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