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Pigments and coloring
Cobalt blue glass
Cobalt-colored glass
Before the 19th century, the predominant use of cobalt was as pigment. Since the Middle Ages, it has been involved in the production of smalt, a blue colored glass. Smalt is produced by melting a mixture of the roasted mineral smaltite, quartz and potassium carbonate, yielding a dark blue silicate glass which is ground after the production.[59] Smalt was widely used for the coloration of glass and as pigment for paintings.[60] In 1780, Sven Rinman discovered cobalt green and in 1802 Louis Jacques Thénard discovered cobalt blue.[61] The two varieties of cobalt blue, cobalt aluminate and cobalt green (a mixture of cobalt(II) oxide and zinc oxide), were used as pigments for paintings because of their superior stability.[62][63]
[edit] Radioisotopes
Cobalt-60 (Co-60 or 60Co) is useful as a gamma ray source because it can be produced in predictable quantity and high activity by bombarding cobalt with neutrons. It produces two gamma rays with energies of 1.17 and 1.33 MeV.[19][64]
Its uses include external beam radiotherapy, sterilization of medical supplies and medical waste, radiation treatment of foods for sterilization (cold pasteurization),[65] industrial radiography (e.g. weld integrity radiographs), density measurements (e.g. concrete density measurements), and tank fill height switches. The metal has the unfortunate habit of producing a fine dust, causing problems with radiation protection. Cobalt from radiotherapy machines has been a serious hazard when not disposed of properly, and one of the worst radiation contamination accidents in North America occurred in 1984, after a discarded radiotherapy unit containing cobalt-60 was mistakenly disassembled in a junkyard in Juarez, Mexico.[66][67]
Cobalt-60 has a radioactive half-life of 5.27 years. This decrease in activity requires periodic replacement of the sources used in radiotherapy and is one reason why cobalt machines have been largely replaced by linear accelerators in modern radiation therapy.[68]
Cobalt-57 (Co-57 or 57Co) is a cobalt radioisotope most often used in medical tests, as a radiolabel for vitamin B12 uptake, and for the Schilling test. Cobalt-57 is used as a source in Mössbauer spectroscopy and is one of several possible sources in X-ray fluorescence devices.[69][70]
Nuclear weapon designs could intentionally incorporate 59Co, some of which would be activated in a nuclear explosion to produce 60Co. The 60Co, dispersed as nuclear fallout, creates what is sometimes called a cobalt bomb.[71]
[edit] Other uses
Other uses of cobalt are in electroplating, owing to its attractive appearance, hardness and resistance to oxidation,[72] and as ground coats for porcelain enamels.[73]