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2008-D LMC Improper Annealing?

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United States
29 Posts
 Posted 01/25/2023  10:33 pm  Show Profile   Bookmark this reply Add Numismax to your friends list
I'd like to know if there's any value with this improper plating issue?


Below are some examples of coins I experimented with to try and replicate what the first 2 responders said it was.

First is one done through heat transfer. I stood a bolt on end and placed the penny on top. Then heated the base of the bolt until I saw the slightest color change. The damage you see happened during the cooling process.

2008-D-LMC-Improper-Annealing?
2008-D-LMC-Improper-Annealing?

Next penny I created by holding it above a Bic lighter with the flame about .25" away from the center of the cent. I stopped as soon as I noticed the copper plating vanish. As seen here, the coin has changed to a more golden hue and the plating vanished from the field quicker than the relief. Where it's thicker. Hard to tell in the pics but there is slight pink-violet "toning" to the area of exposed zinc and copper plating.

2008-D-LMC-Improper-Annealing?
2008-D-LMC-Improper-Annealing?

Third up is one I used a Hobbyist torch. This one was held away in the same fashion as the Bic lighter. Here you can see again, most of the removed copper plating took place in the field rather than centered over Lincoln, where the flame was concentrated. You can also see some of the copper plating removed from the reverse as well as the whole coin is discolored.

2008-D-LMC-Improper-Annealing?
2008-D-LMC-Improper-Annealing?

Lastly, this one was torched as well with the hobbyist torch. This time held with the flame kissing the coin for a second until the slightest color change. This time we got a little bit more centralized copper removal over the relief. However there is still major discoloration/"toning" to the entire coin and between the pillars on the reverse.

2008-D-LMC-Improper-Annealing?
2008-D-LMC-Improper-Annealing?

And all of them together on the reverse to show the color change throughout all of them. The far left is an untouched run of the mill Lincoln Cent.

2008-D-LMC-Improper-Annealing?
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Canada
6244 Posts
 Posted 01/25/2023  11:49 pm  Show Profile   Bookmark this reply Add silviosi to your friends list
This it is not electroplating default. the heat on coins can come from different sources and at different intensities and also different kind of heat. The color of the zinc it is a heat zinc and not as it is in rolls before plating. The coin show a progression of the color transformation also on the Cu which it is from heat source. On this coin the heat was from bottom to up and more concentrate middle left. No such Cu small bulbs will be on fail electroplating.
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United States
29 Posts
 Posted 01/26/2023  12:28 am  Show Profile   Bookmark this reply Add Numismax to your friends list
Silviosi, thank you for your response. What does "Cu" stand for?
And what coin are you referring to when you say the heat came from the bottom up? How would you go about recreating what is displayed in the first post? There is no progression color transformation on the original coin posted and zero discoloration on the reverse. Which I think would be impossible if there was a heat source on that side. Color transformation from heat will go from copper (original plating) - yellow - zinc with pinkish hue at the edges of the yellow and zinc. Something the original coin shows no sign of. No matter what angle it's viewed from.

What other forms of heat should I experiment with? Electricity? A slower lower heat from heat transfer? Should I lay it on top of my wall heater for a week? Maybe a heat gun? Would it be possible to get a heat gun hot enough to remove the copper plating? Even if it would be, I would think I would need to concentrate the airflow with something like a funneled tip. Otherwise the flow would be to broad and encompass the entire coin.

Just trying to wrap my brain around the whole "it was caused by heat" stigma. Because if that were the case. We should be able to find a way to recreate it. I'm willing to try just about anything within my abilities.
Edited by Numismax
01/26/2023 12:30 am
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 Posted 01/26/2023  02:30 am  Show Profile   Bookmark this reply Add silviosi to your friends list
Cu stand for cooper and Zn stand for zinc (proprieties base of in periodic tables of Mendeleev). Natural color of the Zn is grey bluish. After mill it is very shiny and the blanks of Zn are shiny. When heat below 400 deg Celsius (419 deg is melting point) due to the ZnO (zinc oxide) become yellow and when become cool will go back to the natural state color which it is grey bluish. This it is the color of your original coin photo. If was not plated was suppose to be white gray.

Enough, I will not made here a course in metallurgical chemistry.
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 Posted 01/26/2023  04:00 am  Show Profile   Bookmark this reply Add John1 to your friends list
I am surprised the coin did not just melt away using anything other a bic lighter. I remember when the zinc cents first came out, I used a plumbers propane torch and the coin vaporized away.
John1
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 Posted 01/26/2023  5:43 pm  Show Profile   Bookmark this reply Add Cujohn to your friends list
Numismax, Nice you are doing experiments. Now you see how heat damages plated cents. As Silviosi stated the melting point for zinc is almost 800 degrees f. It would be almost imposable to heat a zincoln and keep it at a point to melt the copper plaiting off of a coin without going too far and melting the zinc. You need just enough heat to expand the zinc core enough to crack the copper plating so it falls off.
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United States
29 Posts
 Posted 01/26/2023  6:08 pm  Show Profile   Bookmark this reply Add Numismax to your friends list

Quote:
You need just enough heat to expand the zinc core enough to crack the copper plating so it falls off.


Which, to me at least, would be impossible without the copper layer showing signs of discoloration from being heated.
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 Posted 01/26/2023  6:29 pm  Show Profile   Bookmark this reply Add silviosi to your friends list
@Numismax Hey Man, I do not understand where you want to go? All Californian like to convince they are right? this happened in the last time here.

You has the choice to go to Long Beach Show and PCGS will grad your coin free. The show it is in the begin of February, and then please comeback and show us we are out of the realty.

You do not has any knowledge of Chemistry, Calorimetry and Metallurgical Science, please do not go there if you do not has the background.

I was very glad to see a really missing plating on coin, almost on that part of the coin. Reason it is because the plating on electroplating start with the middle of the coin and not with the border. Explanation? :The most negative ions of the Zn are concentrate in the middle and the anions are most on the sides. Do you want the formula?

Come back with the PCGS slab.
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United States
29 Posts
 Posted 01/26/2023  7:34 pm  Show Profile   Bookmark this reply Add Numismax to your friends list
@silviosi, I do not appreciate the derogatory statements toward Californian nor my level of intellect. If I do not understand something, then isn't that the perfect opportunity to dive in and learn? The whole point in me joining this community is to LEARN. The difficult part I'm having is the language barrier we have. No to offend you, but I have to read your statements over and over to make sure I'm understanding you.

I'm still unsure if you think this was caused pre or post minting.

I'm not trying to prove that I am right. I am just a curious soul. It was suggested that applied heat caused this issue post minting. If that is the case. How might one suggest it was done? I tried a few different ways from the aforementioned above.

I can try copper plating a coin to see for myself how it concentrates in the center first. But aren't the metal sheets plated before the blanks are punched? So plating a coin wouldn't be the same. If I do try plating a coin. How would you recommend I suspend the coin in the copper sulfate solution without the hardware effecting the plating? Alligator clips would leave uneven copper plating where it's secured to the coin. Could I set the coin on the bottom of the glass beaker? Would the side on the glass get coated? I will look into this later.

Thank you for the suggestion on the coin show. Maybe I can get the time to make it there.
Edited by Numismax
01/26/2023 7:38 pm
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 Posted 01/26/2023  8:14 pm  Show Profile   Bookmark this reply Add Cujohn to your friends list
Numismax You keep doing your experiments. The blanks are plated after they are punched out. If they were plated before, the edge would not be plated and the zinc would show. They are tumbled in a solution to plate them.
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 Posted 01/26/2023  8:22 pm  Show Profile   Bookmark this reply Add Cujohn to your friends list
2008-D-LMC-Improper-Annealing? This are some of the ones I found in string rolls.
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 Posted 01/26/2023  8:35 pm  Show Profile   Bookmark this reply Add Petespockets55 to your friends list
I've always thought this centralized lack of plating was caused by an error in the plating process.
As if two zinc blanks stuck together somehow and kept the copper from plating the area between the blanks.
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 Posted 01/26/2023  8:58 pm  Show Profile   Bookmark this reply Add silviosi to your friends list
@ Cu : the color is a normal Zn who come back to his normal stage.
@ PETE: Normal the blanks is suppose to be clean after blanking?!!!? I like your hypotheses.

Me I supposes some could be from the Heats of the Dies. In time I present to the Mint the Document about over heat of the Dies and the danger for the production quality, but as the Mint is do not come back to you.

@Numismax: Far from me to offend you, but to go more far will be complicate. I speak scientific dialect and not the common language, I teaches in DC Mc Hill, in Corpus Christy in Montreal McGill but science. I had residents from over the word and no problems till here sometimes some persons do not accept my way to show what is my opinion and them to analyze what it is..

Is very good to be curious and try to learn and here it is the place for the coins not the forensic of the coins.


PS: The electroplating of the blanks do not use copper sulphate
Edited by silviosi
01/26/2023 9:00 pm
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 Posted 01/26/2023  11:04 pm  Show Profile   Check datadragon's eBay Listings Bookmark this reply Add datadragon to your friends list
Here are some diagnostics also for future reference, check if there is any slightly below weight differences.
https://www.coinworld.com/news/us-c...nghouse.html and https://conecaonline.org/unplated-lincolns/
Edited by datadragon
01/26/2023 11:17 pm
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 Posted 01/26/2023  11:38 pm  Show Profile   Bookmark this reply Add silviosi to your friends list
Excellent DATA. You nail all the suppositions here. PM me to has an interesting Doc for an DATA Dragon.
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