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2008 D LMC Improper Annealing?

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 Posted 01/25/2023  3:06 pm Show Profile   Bookmark this topic Add Numismax to your friends list Get a Link to this Message
Found this one in my change this past month. Am I correct in my labeling? Or is it Incomplete Plating?



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 Posted 01/25/2023  3:10 pm  Show Profile   Bookmark this reply Add coop to your friends list Get a Link to this Reply
Looks like a heated coin with a lighter. Just a damaged coin now.
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 Posted 01/25/2023  3:11 pm  Show Profile   Bookmark this reply Add ijn1944 to your friends list Get a Link to this Reply
Possibility of the obverse being exposed briefly to extreme heat--perhaps a hobby-grade torch.
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 Posted 01/25/2023  3:35 pm  Show Profile   Bookmark this reply Add John1 to your friends list Get a Link to this Reply

We get this question a few times every year. Some say a cigarette lighter some say a plating issue. I think one of the TPGs have slabbed a sample. I think it is a plating issue. If I was you, I would put it in a 2x2 holder just in case.
John1
( I'm no pro, it's just my humble opinion )
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 Posted 01/25/2023  3:44 pm  Show Profile   Bookmark this reply Add Numismax to your friends list Get a Link to this Reply
I saw a graded nickel that looked similar (colors were opposite) But it sold for $125. It was highlighted by Couch Collectables yesterday on Instagram.

I recently took coins and heated them up with a Bic lighter and a small hobby torch and the effects were no where near what this coin shows. There was always other discoloration that appeared. The copper darkened to a red color and also show a pinkish/purple luster.

I will update with later pics of my flamed experimentation.

Edited by Numismax
01/25/2023 3:45 pm
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 Posted 01/25/2023  3:50 pm  Show Profile   Bookmark this reply Add Numismax to your friends list Get a Link to this Reply
@John1
Quote:
I would put it in a 2x2 holder just in case.


I have. Only took it out for picture taking.
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 Posted 01/25/2023  5:57 pm  Show Profile   Bookmark this reply Add Cujohn to your friends list Get a Link to this Reply
As John stated above. This is a plating problem. I have 30 or 40 of them that came out of string rolls in 95. People here seem to think there are a lot of cigarette lighters still around and people heat them up and throw a coin on them as if that low of heat will disintegrate the copper plating and not the zinc. As for the nickels, there are annealing problems on some. I think they are mostly in the late 50s.
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 Posted 01/25/2023  6:13 pm  Show Profile   Bookmark this reply Add Numismax to your friends list Get a Link to this Reply
Thanks Cujohn

I've spent far too long trying to upload the photos of the test pieces involving heat but have not been able to upload more pics for the last 2hrs for whatever reason.

See thread http://goccf.com/t/438223 for my problem

If the others were more familiar with heated coins. It should be pretty plain to see this isn't the case. At least not in my testing. I will still upload the images once I get the uploading issue resolved.

The nickel I mentioned was a 2004
Edited by Numismax
01/25/2023 6:24 pm
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 Posted 01/25/2023  10:33 pm  Show Profile   Bookmark this reply Add Numismax to your friends list Get a Link to this Reply
I'd like to know if there's any value with this improper plating issue?


Below are some examples of coins I experimented with to try and replicate what the first 2 responders said it was.

First is one done through heat transfer. I stood a bolt on end and placed the penny on top. Then heated the base of the bolt until I saw the slightest color change. The damage you see happened during the cooling process.




Next penny I created by holding it above a Bic lighter with the flame about .25" away from the center of the cent. I stopped as soon as I noticed the copper plating vanish. As seen here, the coin has changed to a more golden hue and the plating vanished from the field quicker than the relief. Where it's thicker. Hard to tell in the pics but there is slight pink-violet "toning" to the area of exposed zinc and copper plating.




Third up is one I used a Hobbyist torch. This one was held away in the same fashion as the Bic lighter. Here you can see again, most of the removed copper plating took place in the field rather than centered over Lincoln, where the flame was concentrated. You can also see some of the copper plating removed from the reverse as well as the whole coin is discolored.




Lastly, this one was torched as well with the hobbyist torch. This time held with the flame kissing the coin for a second until the slightest color change. This time we got a little bit more centralized copper removal over the relief. However there is still major discoloration/"toning" to the entire coin and between the pillars on the reverse.




And all of them together on the reverse to show the color change throughout all of them. The far left is an untouched run of the mill Lincoln cent.

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 Posted 01/25/2023  11:49 pm  Show Profile   Bookmark this reply Add silviosi to your friends list Get a Link to this Reply
This it is not electroplating default. the heat on coins can come from different sources and at different intensities and also different kind of heat. The color of the zinc it is a heat zinc and not as it is in rolls before plating. The coin show a progression of the color transformation also on the Cu which it is from heat source. On this coin the heat was from bottom to up and more concentrate middle left. No such Cu small bulbs will be on fail electroplating.
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 Posted 01/26/2023  12:28 am  Show Profile   Bookmark this reply Add Numismax to your friends list Get a Link to this Reply
Silviosi, thank you for your response. What does "Cu" stand for?
And what coin are you referring to when you say the heat came from the bottom up? How would you go about recreating what is displayed in the first post? There is no progression color transformation on the original coin posted and zero discoloration on the reverse. Which I think would be impossible if there was a heat source on that side. Color transformation from heat will go from copper (original plating) - yellow - zinc with pinkish hue at the edges of the yellow and zinc. Something the original coin shows no sign of. No matter what angle it's viewed from.

What other forms of heat should I experiment with? Electricity? A slower lower heat from heat transfer? Should I lay it on top of my wall heater for a week? Maybe a heat gun? Would it be possible to get a heat gun hot enough to remove the copper plating? Even if it would be, I would think I would need to concentrate the airflow with something like a funneled tip. Otherwise the flow would be to broad and encompass the entire coin.

Just trying to wrap my brain around the whole "it was caused by heat" stigma. Because if that were the case. We should be able to find a way to recreate it. I'm willing to try just about anything within my abilities.
Edited by Numismax
01/26/2023 12:30 am
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 Posted 01/26/2023  02:30 am  Show Profile   Bookmark this reply Add silviosi to your friends list Get a Link to this Reply
Cu stand for cooper and Zn stand for zinc (proprieties base of in periodic tables of Mendeleev). Natural color of the Zn is grey bluish. After mill it is very shiny and the blanks of Zn are shiny. When heat below 400 deg Celsius (419 deg is melting point) due to the ZnO (zinc oxide) become yellow and when become cool will go back to the natural state color which it is grey bluish. This it is the color of your original coin photo. If was not plated was suppose to be white gray.

Enough, I will not made here a course in metallurgical chemistry.
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 Posted 01/26/2023  04:00 am  Show Profile   Bookmark this reply Add John1 to your friends list Get a Link to this Reply
I am surprised the coin did not just melt away using anything other a bic lighter. I remember when the zinc cents first came out, I used a plumbers propane torch and the coin vaporized away.
John1
( I'm no pro, it's just my humble opinion )
Searched 6.5 +/- Million Cents Since 1971
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 Posted 01/26/2023  5:43 pm  Show Profile   Bookmark this reply Add Cujohn to your friends list Get a Link to this Reply
Numismax, Nice you are doing experiments. Now you see how heat damages plated cents. As Silviosi stated the melting point for zinc is almost 800 degrees f. It would be almost imposable to heat a zincoln and keep it at a point to melt the copper plaiting off of a coin without going too far and melting the zinc. You need just enough heat to expand the zinc core enough to crack the copper plating so it falls off.
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 Posted 01/26/2023  6:08 pm  Show Profile   Bookmark this reply Add Numismax to your friends list Get a Link to this Reply

Quote:
You need just enough heat to expand the zinc core enough to crack the copper plating so it falls off.


Which, to me at least, would be impossible without the copper layer showing signs of discoloration from being heated.
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