The portrait of Bolivar looks like it was copied from the portrait used on Venezuelan coins for the last 100+ years. It could be an item from Venezuela. But, of course, Simon Bolivar is a hero in more than one South American country so there are a lot of places this could have come from.
My best guess is that it's a privately made silver bar, perhaps from Venezuela but with no official government authorization, sold as an investment and collectible to a Bolivar-loving population. The little gold insert means that it's not simply a bullion item - it is meant to be some kind of art, as well.
Unfortunately I don't speak Spanish, so that's about as far as I can go.
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