Hello and welcome.

Your first coin has "environmental damage". An aluminium-bronze coin turning dark might be caused by several things, but the two commonest are spending some time buried in soil before being dug up again, or spending some time immersed in chlorinated water such as as a swimming pool or public fountain.
As for your second coin, several things may have happened. There may have been a pinhole in the mint bag directly above the spot, allowing air or whatever noxious gases the bag was exposed to, to react with the coin only in that spot. Or, it may have had something spilled on it before being put into the bag. It does not really look like a defect in the alloy, so cannot truly be called a "mint error", even if what happened to it did happen before it left the mint.
Don't say "infinitely" when you mean "very"; otherwise, you'll have no word left when you want to talk about something really infinite. - C. S. Lewis