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What Would Cause A Soaking Coin To Do This?

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bobbyhelmet's Avatar
United Kingdom
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 Posted 01/23/2012  09:59 am Show Profile   Bookmark this topic Add bobbyhelmet to your friends list Get a Link to this Message Number of Subscribers

What-Would-Cause-A-Soaking-Coin-To-Do-This?
What-Would-Cause-A-Soaking-Coin-To-Do-This?
What-Would-Cause-A-Soaking-Coin-To-Do-This?


The coin has not been coated in anything but over the space of about 24 hours when soaking in distilled water it emits and becomes covered in the above white substance.

The substance is milky and has no smell - its the second time its done it, I didn't give it much thought at first so just changed the water and put it back. The coin does not seem to be disintegrating or loosing surface detail.
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jessvc1's Avatar
United States
2596 Posts
 Posted 01/23/2012  10:27 am  Show Profile   Bookmark this reply Add jessvc1 to your friends list Get a Link to this Reply
I couldn't tell you, if its not harming the coin I guess "we'll" just have to wait and see how it turns out. Hope it will turns out good. Looks like you have some nice coins in that bowl. Is that a provincial its leaning on?
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bobbyhelmet's Avatar
United Kingdom
2838 Posts
 Posted 01/23/2012  11:10 am  Show Profile   Bookmark this reply Add bobbyhelmet to your friends list Get a Link to this Reply

Quote:
Is that a provincial its leaning on?


Yep - its a year 5 Philip from Viminacium
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DVCollector's Avatar
United States
10045 Posts
 Posted 01/23/2012  12:11 pm  Show Profile   Bookmark this reply Add DVCollector to your friends list Get a Link to this Reply
Wow...that's interesting, I've never seen such a thing.
Is the coin bronze? It appears to be leaching out something.
I would soak that coin by itself, so it doesn't contaminate others.
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echizento's Avatar
United States
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 Posted 01/23/2012  12:14 pm  Show Profile   Bookmark this reply Add echizento to your friends list Get a Link to this Reply
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bobbyhelmet's Avatar
United Kingdom
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 Posted 01/23/2012  12:22 pm  Show Profile   Bookmark this reply Add bobbyhelmet to your friends list Get a Link to this Reply
I too have never seen anything like it.

The coin is bronze - this is it before soaking, it looked clean and was not covered in anything:
What-Would-Cause-A-Soaking-Coin-To-Do-This?


I think your right, I've removed it to its own pot and its soaking to see if it happens for a third time.

I had thought it was salts originally but don't believe that any more.
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VisigothKing's Avatar
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 Posted 01/23/2012  1:26 pm  Show Profile   Bookmark this reply Add VisigothKing to your friends list Get a Link to this Reply
Interesting. I got to watch out for this (or anything else that looks questionable) when I start cleaning ancients (hopefully in the near future).
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Gil-galad's Avatar
United States
2044 Posts
 Posted 01/23/2012  1:28 pm  Show Profile   Bookmark this reply Add Gil-galad to your friends list Get a Link to this Reply
This may seem unlikely but what if the coin has lead mixed in with the copper?

I have seen ancient lead coins look white.
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DVCollector's Avatar
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 Posted 01/23/2012  2:27 pm  Show Profile   Bookmark this reply Add DVCollector to your friends list Get a Link to this Reply
I'm no chemist, but it's fun to guess what happened here.
If there was "white lead" in the coin. It's pretty stable; I think you would see it before the soak.
I've seen waxes turn white in water, such as water spots on a coffee table.
Perhaps the coin was waxed?
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Sap's Avatar
Australia
16868 Posts
 Posted 01/23/2012  5:18 pm  Show Profile   Bookmark this reply Add Sap to your friends list Get a Link to this Reply
To react that fast in just distilled water, it can't be anything naturally residing on a coin that's already been partially cleaned. I suspect it's some kind of coating or perhaps artificial patination that's coming off.

What's the little white ring near the rim at 5 o'clock? It's looking suspiciously like a filled hole to me.

From the "before" pic, it looked clean enough - what made you decide to soak it?
Don't say "infinitely" when you mean "very"; otherwise, you'll have no word left when you want to talk about something really infinite. - C. S. Lewis
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Fatboy's Avatar
United States
313 Posts
 Posted 01/23/2012  5:31 pm  Show Profile   Bookmark this reply Add Fatboy to your friends list Get a Link to this Reply
My guess
Chemical reaction with the other coins and the water?
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 Posted 01/23/2012  6:47 pm  Show Profile   Bookmark this reply Add Doucet to your friends list Get a Link to this Reply
My guess would have to be a very old coating of wax that you didn't notice before soaking.

Take a little of it and put it on a glass surface and let it dry. It might help to determine if it a waxy substance or something else like a varnish or a metallic substance.
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sel_69l's Avatar
Australia
21788 Posts
 Posted 01/24/2012  06:48 am  Show Profile   Bookmark this reply Add sel_69l to your friends list Get a Link to this Reply
I suspect that the coin has some kind of organic partly water soluble coating on it. The water seems to have softened and expanded it. Does the coin have a slimy feel when wet?

That little white ring that Sap spotted suggests to me that the coin may have been laquered, perhaps as a method of preserving it. I have sprayed acryllic laquer on a coin myself by way of experimentation.

Try soaking it in kerosene, then methylated spirits, then acetone, then let it dry naturally.

All of the abovementioned are organic solvents, but the methylated spirits has a hydroxide radical (OH)-, which is the same as water when it splits into a H+ and an (OH)- radical, which explains why water is a good solvent for so many things.

The other two are purely organic solvents. The high volatility of the acetone will eliminate the need to dry it. So will the methylated spirits.
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biggfredd's Avatar
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 Posted 01/24/2012  07:28 am  Show Profile   Bookmark this reply Add biggfredd to your friends list Get a Link to this Reply
Could it be like the electrolysis caused by dissimilar metals in contact?
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sel_69l's Avatar
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 Posted 01/24/2012  07:39 am  Show Profile   Bookmark this reply Add sel_69l to your friends list Get a Link to this Reply
biggfredd: I don't think so. bobbbyhelmet has not reported any loss of metal from the coin.
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biggfredd's Avatar
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 Posted 01/24/2012  08:05 am  Show Profile   Bookmark this reply Add biggfredd to your friends list Get a Link to this Reply
For the right side up folks, methylated spirits = denatured alkyhaul, commonly 90% ethanol and 10% methanol.
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