The 50c looks like
PMD to me, although it may have been caused naturally.
Over the years, I have seen a few copper nickel coins, of all countries, that quite obviously look to be copper, but in fact, are not.
An aggressive environment can cause this over a period of years, which would also require to coin to be out of circulation to allow the coin to change appearance, especially if the change was happening in natural circumstances.
Differential 'toning' such as this could occur if the coins were heaped, not stacked.
I also see the possibility of a 'pub coin', to fool unknowing intended buyers, but it could equally also be just the result of 'shed job' with some innocent fooling around.
I do that with modern circulating coins (rarely) just to entertain myself. They all go back into circulation , because I can't see any point in keeping them.