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Replies: 18 / Views: 24,198 |
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Pillar of the Community
 United States
2703 Posts |
Great setup, Kurt! Thanks for explaining the calculation. Does that agree with the composition for the coin listed in Krause? (I don't have my books handy) I am a little surprised that it would be so debased.
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Pillar of the Community
 United States
5318 Posts |
Tom, I did find an online reference which gives the silver composition as .562, which is a bit different than my result--I'm going to re-test to confirm. I also did a "control group" test of bronze coins, comparing to some modern silver coinage with interesting results! But if these 8 Skillings were debased at all, I wouldn't be too surprised since Denmark was engaged in war at the time. Great coin--thanks again! 
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Valued Member
 United States
306 Posts |
Thank you for the information. I've been looking for a method to determine the minting dates for the Ethiopian fifty cent coin. It has a frozen date and there are 80% and 70% silver coins depending on the when it was minted.
One question about wear: Does anyone know how much weight a coin looses with wear such as a Good grade vs. Uncirculated?
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Pillar of the Community
 United States
5318 Posts |
I tested this coin again (3 more times actually), and the SG is closer to 9.1, which suggests the silver content is significantly lower than .562 (see table). Weighing 2.91gr against the 3.057gr specification, it's interesting how this difference is proportional to a lower silver content suggested by the SG result. Table of SG for silver content--with remainder copper: .999 = 10.49 .925 = 10.36 .900 = 10.31 .850 = 10.23 .800 = 10.17 .750 = 10.08 .600 = 9.84 .500 = 9.68 .400 = 9.53 .300 = 9.38 .200 = 9.23 Quote:
...It has a frozen date and there are 80% and 70% silver coins depending on the when it was minted. That could help, provided the silver content was accurately alloyed. My tests so far suggest silver content isn't consistently controlled.
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Pillar of the Community
United Kingdom
1077 Posts |
Can I use De-ionised water in place of distilled?
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Bedrock of the Community
United States
12437 Posts |
Quote: Can I use De-ionised water in place of distilled? I do not see any reason why DI water could not be used, it is just that more people have access to distilled than DI.
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Pillar of the Community
United Kingdom
1077 Posts |
Thanks for that biokemist6. I can get de-ionised at the supermarket, but not distilled.
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Pillar of the Community
United States
3294 Posts |
Wouldn't this be easier if you measured the volume of the coin directly, using a plastic coin tube with water of a measured depth, then placing the coin into to tube and measuring the new depth? You then find the diameter of the inside of the coin tube, and you find the volume of the coin. Combined with an accurate weight measurement and you have the density of the coin.
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Bedrock of the Community
United States
20753 Posts |
Quote:
I do not see any reason why DI water could not be used, it is just that more people have access to distilled than DI.
Many manufacturers advertise DI water and it has turned out to be either tap water filtered or spring water. Some companies have been noted for doing this and there is no law against it so they can continue as before. Best to use Distilled. Nice experiment. Works best with UNC coins though. It si really difficult to determine the metallic loss of a coin from wear though. And as to those Chinese fakes. One of the problems is some use the exact same Silver as the original coins. Their purpose is not to cheat people out of Silver, it's to sell coins worth a lot more than the face or spot value. Many are even more pure than the originals and go for hundreds or thousands of dollars. KurtS, have you tried this with other than metal for a harness? Just wondering about the chances of scratches from a metallic harness.
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Pillar of the Community
United Kingdom
1077 Posts |
I also thought that a different harness might be better and wondered if it was ok. I thought about a rubber band double crossed around the coin and attached to thread.
The de-ionised water I have seen is from a reputable, very large company and there are laws in the UK about mis description, I don't personally think this company would take the chance of calling a product something it's not, but I see your point.
By the same token, if this is the case, how do you know distilled water has been distilled?
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Valued Member
Ireland
498 Posts |
Very nice info.
Eureka. Takes time to absorb all the info very nice thread. weight,mass,specific gravity,metal content,troy ounce.
other are reading the lower part of distilled water in test tube.
if may apply in coins when they change the metal content like the GB predecimal silver and predecimal copper that ay goes also to other comonwealth coins struck in GB and their metal compositons.
shipwreckcoins is there specific gravity also change? seen some on TV that a metal support in oil rigs change its shape and metal composition maybe due to force and pressure perhaps there specific gravity also change.
Edited by josie 05/14/2009 5:05 pm
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Valued Member
Ireland
498 Posts |
Physics,chemistry.
elctricity,electronics,much more difficult to find the conductibility of a coin if it is high conductable metal content,just like a homemade tester with several side by side light emiting device in circuit form for measuring a poor conductor to high conductibilty,to many variables to pyx,it is a start homemade device to test the metal content other are using x ray flourencence in universities for knowing the metal content or composition.
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Valued Member
United States
106 Posts |
I'm pretty sure that the method of calculating the specific gravity is very good, but in terms of calculating the percentage composition for silver copper alloys, I wondered if you have to correct for non linearity in the density. For example, I've worked in the ethanol industry. If you take a liter of ethanol, and a liter of water, and mix them together, the result is only 1.92 liters. So I made the calculation for silver / copper.
Silver and copper form a eutectic alloy of 0.719 Ag + 0.281 Cu. If you have more silver than that, the coin will be partially the eutectic alloy and partially pure silver (google eutectic silver copper to learn more). With less silver, it will be partially pure copper and partially the eutectic mixture. The eutectic mixture calculates to have a density of 1/(0.719/10.49 + 0.281/8.96) = 10.0097. The specific density of the eutectic alloy, (which is sold as brazing supplies, for example, as "Silvaloy") is 10.009. So the calculation works, and this will give you the right answer.
As far as why the coin came out 0.75 silver, I think it's likely because of errors in your measurements. You shouldn't have Sa = Sw, for example. And if you make an error of 0.01 in your measurement of any one of Wa, Sa, Sw, Sa it will give an error of about 3% in your calculated specific gravity, and around 30% in your calculation for the percentage silver. (To see this, change one of your inputs to the calculation by 0.01 and recalculate.) So for the accuracy of your measurements, the coin could have just about any silver percentage.
As far as improving this, it would be better to have a bunch of coins so you're not looking for small differences. Or get a much more accurate scale. And since what you're really interested in is the difference in weight between in air and in water, it would be better to design the experiment so you measure this difference directly instead of subtracting absolute measurements. That could be done by arranging for some counterbalance which is also either in water or air. Hmmmmmm.
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Valued Member
United States
266 Posts |
One possible source of error is assuming that they started off with .999 pure metals. Which in 1702 I really doubt is true. Any other metals in the mix will throw off your results. It is possible that older coins were being melted to make the new ones, adding some amount of tin/zinc or who knows what else. The only way to know for sure , as Josie has mentioned is xray fluorescence. I used to work as a Service tech on those Xrays but I quit that job and no longer have access to them
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Valued Member
Ireland
498 Posts |
Nice thread.
I did weigh some of GB copper pennies and half pennies also Ireland digital scale by weight and troy ounce,even try to weigh the coins of GB those that are silver those that are in boundaries from .7 to .5 percent something like that just incase other composition struck in different composition no luck.
Quite difficult have to weigh the coppers three times by wieght and troy ounce at least I did try,since GB pennies have different composition and an expert mention about pyx the variables are factors increase it fun like a playground,and it compose of 3 metals,others are saying using MD having different sound for different metals.
Nice additional info about the specific gravity,I did even seach on the web about condutivity or electricity,circular rod is more good form of conductor but applied with coins,it might be difficult just like a tester,like a small diode will emit a small amount of electricity will maybe know the conductibility and metal or its composition,Im not an electrician do not know how to made one.
Even thinking electron configuration and conductibility.
Maybe combination of all.
Hope there will be at home alternative for x ray flourecence expert say its not easy to acces and dont know if it is expensive.
Good thou nice math problem for math book.physics and its applied.
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Replies: 18 / Views: 24,198 |
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