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Cleaning Verdigris From Silver Coins. One Technique

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austrokiwi's Avatar
2087 Posts
 Posted 03/10/2014  09:42 am Show Profile   Bookmark this topic Add austrokiwi to your friends list Get a Link to this Message Number of Subscribers
This is a chemical process and should only be used, IMHO, for gap fillers where you wish to prevent further deteriation and stabilise the coin.

I know this works for silver coin...I suspect with copper you might have a disaster.

Materials:

Household Soda
Boiling water
Glass bowl
Aluminium foil


Technique: line the glass bowl with Aluminium foil, then put a handful of Household soda in the bowl. Pour on the boiling water. Stir to dissolve the Soda. While the water is still as close to boiling drop in the coin. Wait a maximum of 10 minutes then flip the coin over. Wait again a maximum of 10 minutes then take the coin out..If you have done it long enough the verdigris will be gone( actually it is converted back to copper!) and the silver will be bright and shiny. The process uses the aluminium foil as a sacrificial metal. When the coin is placed in the bowl in contact with the foil, the oxides on the coin are reduced back to silver ( the verdigris is reduced back to copper). Rinse the coin well in water. To make doubly sure then soak it in acetone. Here are some B4 and after photos. Obviously the technique won't restore a coin but it will kill the verdigris. I also like it because it leaves obvious signs ( copper sheen) on the coin where the verdigris was..so it can't be mistaken for a perfect example. Sorry for the differences in photo size, note the coin now looks very bright the photo is deceptive I wanted to illustrate clearly the copper sheen.

Photo B4:



Cleaning-Verdigris-From-Silver-Coins.-One-Technique

Photo after:


Cleaning-Verdigris-From-Silver-Coins.-One-Technique
Edited by austrokiwi
03/10/2014 09:48 am
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awildeheart's Avatar
Australia
295 Posts
 Posted 03/10/2014  11:26 am  Show Profile   Bookmark this reply Add awildeheart to your friends list Get a Link to this Reply
Hello Austrokiwi, for us here in Australia, what product/chemical do you mean by 'household soda'? I'm guessing it is Sodium Bicarbonate ... but thought it best to double check.
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BadThad's Avatar
United States
19935 Posts
 Posted 03/10/2014  11:35 am  Show Profile   Bookmark this reply Add BadThad to your friends list Get a Link to this Reply
It may work, but it's also an excellent way to permanently damage your coins.
Lincoln Cent Lover!
VERDI-CARE™ INVENTOR
https://verdi.care/
Pillar of the Community
austrokiwi's Avatar
2087 Posts
 Posted 03/10/2014  11:43 am  Show Profile   Bookmark this reply Add austrokiwi to your friends list Get a Link to this Reply

Quote:
I'm guessing it is Sodium Bicarbonate


Yep that will do the job it acts as an electrolyte.


Quote:
It may work, but it's also an excellent way to permanently damage your coins


Not sure what you mean? It works.... it is great for cleaning tarnished silver. With an already damaged coin( with verdigris) its will clean up the verdigris and stabilize the surface. It will not hide the damage done by the verdigris!!

Valued Member
awildeheart's Avatar
Australia
295 Posts
 Posted 03/10/2014  11:57 am  Show Profile   Bookmark this reply Add awildeheart to your friends list Get a Link to this Reply
Well Bad Thad, it would be nice to have access to VerdiCare in Australia ... but unfortunately not all newbie/low budget coin collectors live in the USA.

When postage (JUST postage, not for the actual product itself) is more than $24 to mail a small 60ml bottle here via your ebay store ... VerdiCare suddenly does not seem a viable solution for collectible-but-not-expensive coins that have a small amount of verdigris.

If this process gently stops verdigris on a coin that would otherwise be worthless as the verdigris progresses, then it seems a chance worth taking in my books.
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United States
1666 Posts
 Posted 03/10/2014  9:47 pm  Show Profile   Bookmark this reply Add Numismat to your friends list Get a Link to this Reply
This seems like a more complicated process than just using diluted acetone and xylene to achieve the same effect. And honestly I think that coin looks worse in the after picture than the before picture.
Edited by Numismat
03/10/2014 9:48 pm
Pillar of the Community
austrokiwi's Avatar
2087 Posts
 Posted 03/11/2014  01:49 am  Show Profile   Bookmark this reply Add austrokiwi to your friends list Get a Link to this Reply

Quote:
This seems like a more complicated process than just using diluted acetone and xylene to achieve the same effect. And honestly I think that coin looks worse in the after picture than the before picture.


In real life it actually looks heaps better. If you have some tarnished silver try it on that ( not anything with stones or pearls on it) Actually the reaction is very fast sometimes taking less than 30 seconds. I will try to post a better photo later to day
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BadThad's Avatar
United States
19935 Posts
 Posted 03/12/2014  08:34 am  Show Profile   Bookmark this reply Add BadThad to your friends list Get a Link to this Reply

Quote:
Well Bad Thad, it would be nice to have access to VerdiCare in Australia ... but unfortunately not all newbie/low budget coin collectors live in the USA.

When postage (JUST postage, not for the actual product itself) is more than $24 to mail a small 60ml bottle here via your ebay store ... VerdiCare suddenly does not seem a viable solution for collectible-but-not-expensive coins that have a small amount of verdigris.


Are you blaming me for you living on the other side of the planet?
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VERDI-CARE™ INVENTOR
https://verdi.care/
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BadThad's Avatar
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19935 Posts
 Posted 03/12/2014  08:35 am  Show Profile   Bookmark this reply Add BadThad to your friends list Get a Link to this Reply

Quote:
This seems like a more complicated process than just using diluted acetone and xylene to achieve the same effect. And honestly I think that coin looks worse in the after picture than the before picture.


Verdigris is INSOLUBLE in organic solvents. The primary constituents in verdigris are inorganic salts.
Lincoln Cent Lover!
VERDI-CARE™ INVENTOR
https://verdi.care/
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awildeheart's Avatar
Australia
295 Posts
 Posted 03/12/2014  10:35 am  Show Profile   Bookmark this reply Add awildeheart to your friends list Get a Link to this Reply

Quote:
Are you blaming me for you living on the other side of the planet?


No Bad Thad, but I am blaming you for over-charging way too much for postage. I buy a lot of stuff on the internet from all over the world and rarely pay postage. And the few times I do, it is at a reasonable cost and I don't mind paying it.

BUT paying over $24 postage for a small 60ml bottle of stuff is highway robbery. When I queried it with you, your 'solution' was to recommend I buy double of your product to make the postage costs worthwhile. Not very good customer service relations to suggest an already upset customer doubles their order (doubling the profit to you) to make the most of your inflated shipping costs.

And before you say you have a third party handling the shipping and it is out of your hands, maybe you need to look at finding cheaper shipping options to allow the Aussie coinaholics to purchase your product and spread the VerdiCare love?
Edited by awildeheart
03/12/2014 12:55 pm
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Conder101's Avatar
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17884 Posts
 Posted 03/12/2014  12:13 pm  Show Profile   Bookmark this reply Add Conder101 to your friends list Get a Link to this Reply
The posted procedure will remove tarnish, it will not remove verdigris. It is also pretty much the same as usign a commercial dip. It strips the surface, but uses a base solution instead of an acid one. Either way it causes the same surface damage to the coin and if overdone will strip the luster. Bases can be just as corrosive as acids.
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BadThad's Avatar
United States
19935 Posts
 Posted 03/13/2014  1:41 pm  Show Profile   Bookmark this reply Add BadThad to your friends list Get a Link to this Reply

Quote:
BUT paying over $24 postage for a small 60ml bottle of stuff is highway robbery. When I queried it with you, your 'solution' was to recommend I buy double of your product to make the postage costs worthwhile. Not very good customer service relations to suggest an already upset customer doubles their order (doubling the profit to you) to make the most of your inflated shipping costs


Well, contact USPS and ebay. I offer FREE shipping, they set the prices. I make ZERO DOLLARS from shipping!

Lincoln Cent Lover!
VERDI-CARE™ INVENTOR
https://verdi.care/
Edited by BadThad
03/13/2014 1:43 pm
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austrokiwi's Avatar
2087 Posts
 Posted 03/14/2014  10:06 am  Show Profile   Bookmark this reply Add austrokiwi to your friends list Get a Link to this Reply

Quote:
The posted procedure will remove tarnish, it will not remove verdigris. It is also pretty much the same as usign a commercial dip. It strips the surface, but uses a base solution instead of an acid one. Either way it causes the same surface damage to the coin and if overdone will strip the luster. Bases can be just as corrosive as acids


WRONG! First6 off it is completely different to a dip, Its a sacrificial metal process. Similar to that used to prevent corrosion on Oil rigs(Magnesium blocks) Its an electro-chemical process(like a battery). The coin I posted now has a copper sheen where the verdigris was. The soda only acts as an electrolyte. When the coin touches the the foil some of the foil is corroded while the corrosion on the coin is reversed) this includes the verdigris....Obviously there's some people here who have a commercial interest in putting people off this process. They want to make people use their product rather than something cheaper.Accordingly they are naturally biased against anything that challenges their profits. As I said at the out set I only recommended it for already damaged coins...and look how threatened BadThad was over that!!

Its amazing how commercial interests will rubbish something and misconstrue what it does so as to support their products.

Here is one of the chemical formula's that explains how the silver sulfides are affected in this process( I don't have the formula for the copper compounds in verdigris but copper sulphate is a significant component of verdigris):


3 Ag2S + 2 Al --/> 6 Ag + Al2S3
silver
sulfide aluminum silver aluminium sulfide


Actually I found another name for the process Electrolytic cleaning:

See this entry in Wikipedia and scroll down to Electrolytic cleaning don't be scared of the term "Galvanic corrosion" in this process it is the Aluminium foil that is being corroded

I would suggest the verdi care people stop pushing on this one because some of the research I have done to check how the aluminium foil actually works suggests there are some very real concerns about verdicare Such as: As you remove the verdigris you must be removing some of the coins original metal.
Edited by austrokiwi
03/14/2014 10:51 am
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SsuperDdave's Avatar
United States
23522 Posts
 Posted 03/14/2014  5:41 pm  Show Profile   Bookmark this reply Add SsuperDdave to your friends list Get a Link to this Reply

Quote:
Actually I found another name for the process Electrolytic cleaning:


So, you've just now "discovered" electrolytic cleaning, and all of a sudden you're an expert chemist and coin conservationist?

Forgive me, austrokiwi, but

A correct-but-incomplete understanding is just as wrong as being completely in the dark.
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dei gratia regina's Avatar
United States
25 Posts
 Posted 03/15/2014  09:10 am  Show Profile   Bookmark this reply Add dei gratia regina to your friends list Get a Link to this Reply

Quote:
BUT paying over $24 postage for a small 60ml bottle of stuff is highway robbery.


You going to yell at the maker of the 2x2's for the distributor's high shipping, too?

There have a couple posts by people offering to ship it to members overseas, one by a mod if I remember correctly. Take them up on it if you want to. You lashing out at a manufacturer because of the distributor's policies/ship charge is just plain ignorant.

Regarding the foil 'technique' - while it's great for tarnished silver, what you aren't realizing - or at the least did not state - is that the process takes a bit of the silver with it when it moves to the foil. Your first sentence needs to be bolded and enlarged: This is a chemical process and should only be used, IMHO, for gap fillers where you wish to prevent further deteriation and stabilise the coin. It's a harsher method than a dip. It sounds like you're very new to it, so I'd suggest you proceed with a great deal of caution if you're going to keep doing this to coins.


Quote:
Obviously there's some people here who have a commercial interest in putting people off this process.

Yes. We like our coins undamaged. Sooner or later the ones being killed of any numismatic value in this manner are going to leave your hands, and in the same manner that caution is urged against any other harsh method, other people will warn against it. So yes, I believe many have a commercial interest.
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awildeheart's Avatar
Australia
295 Posts
 Posted 03/15/2014  09:15 am  Show Profile   Bookmark this reply Add awildeheart to your friends list Get a Link to this Reply
SsuperDdave, I'm really surprised a moderator would be so insulting to a forum member.

Bad Thad, your attitude is equally insulting and very surprising for both a business man and a forum member with nearly 11,000 posts on this forum.

This is my last contribution to this public thread, but if you would like to continue the conversation privately then by all means email me.

My last public point addresses Bad Thad's response of
Quote:
Well, contact USPS and ebay.
which totally ignored the point in my prior suggestion of:


Quote:
And before you say you have a third party handling the shipping and it is out of your hands, maybe you need to look at finding cheaper shipping options to allow the Aussie coinaholics to purchase your product and spread the VerdiCare love?


I checked the USPS website and found this much more reasonable postage rate, so why are you charging over $24AUD?:

Cleaning-Verdigris-From-Silver-Coins.-One-Technique
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