Yes, 1996. The silver dollars became sterling silver in 1992 though. In the 2003-2006 sets the silver dollar is .9999 silver. In 2012 there was a proof set with all coins .9999 silver including the penny & loonie and another set where all the coins except the silver dollar were done in copper/nickel/brass. 2013 was just the all .9999 silver set and 2014 has both a completely .9999 silver set and a set where all the coins except the silver dollar are nickel/brass plated steel.



















