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Bronze Disease/Verdigris On Silver Denarius?

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Pillar of the Community
Kefiroth's Avatar
United States
1431 Posts
 Posted 02/23/2018  4:56 pm Show Profile   Bookmark this topic Add Kefiroth to your friends list Get a Link to this Message Number of Subscribers
Hello all,

Lately, I had noticed while examining this denarius of Hadrian under a bright white LED light, some pale-greenish residue on the reverse surface and as well as inside a shallow rim crack.

Not sure if this is just some inert residue that took on a greenish color, or something more insidious. Since this is not one of the later, heavily debased issues, I would think bronze disease would be out of the question, but as there is still some copper content present, I'd just want to be sure. This coin has been stored inside a PVC-free cardboard 2x2.

For what it's worth, a gentle rub with the tip of a toothpick seemed to pick it right up, though I was unable to get the stuff inside the rim.

full coin:
Bronze-Disease/Verdigris-On-Silver-Denarius?

inside the rim crack:
Bronze-Disease/Verdigris-On-Silver-Denarius?

reverse surfaces:
Bronze-Disease/Verdigris-On-Silver-Denarius?


Thanks!
Edited by Kefiroth
02/23/2018 5:25 pm
Bedrock of the Community
sel_69l's Avatar
Australia
21788 Posts
 Posted 02/23/2018  5:48 pm  Show Profile   Bookmark this reply Add sel_69l to your friends list Get a Link to this Reply
I would do an intensive Google search, looking at the various methods of the passivation of verdigris.

In the case of a Hadrian denarius, the alloy is not orichalcum (a zinc-copper brass, found in dupondii and sestertii) or bronze (tin-copper bronze).
The silver alloy in the case of this particular Hadrian denarius has copper, but has more than 50% silver. The high proportion of silver in the alloy has greatly suppressed the formation of verdigris, but not arrested it.

Give consideration as to which approach to the treatment of verdigris, may best suit the treatment of this coin.

I think it is imperative that something must be done. Picking at it with a toothpick would seen to be a good first step. The silver alloy would be very much harder than the wood of a toothpick.
Edited by sel_69l
02/23/2018 6:07 pm
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echizento's Avatar
United States
23731 Posts
 Posted 02/23/2018  5:52 pm  Show Profile   Bookmark this reply Add echizento to your friends list Get a Link to this Reply
It might be some transfer verdigris from the coin being buried with bronze coins. Or the coin could be a fouree, but it doesn't look like one. Also these coins were not 100% silver and it's possible that due to moisture what base metal that was there is leaching out.
Bedrock of the Community
sel_69l's Avatar
Australia
21788 Posts
 Posted 02/23/2018  6:05 pm  Show Profile   Bookmark this reply Add sel_69l to your friends list Get a Link to this Reply
Typically, the purity of the silver in Hadrian denarii is around 85%, but the fact that this particular coin presents with verdigris, suggests to me that the silver content may be (I guess) around 70-75%. The rest of the coin still looks quite silvery, unlike the tendency to blackening with billon (less than 50% silver), coins.

Verdicare may help remove the light surface greenish tinge, but probably won't help in the small green pitted areas.

I agree with what echizento has said.
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