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Green Silver?

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Author Previous TopicReplies: 7 / Views: 1,378Next Topic  
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Scooby Due's Avatar
United States
4000 Posts
 Posted 12/17/2010  11:56 am Show Profile   Bookmark this topic Add Scooby Due to your friends list Get a Link to this Message Number of Subscribers
What has turned these coins into a green, turquoise looking hue? Could it be storage or PVC?
Anyway to save them?


Green-Silver?
Pillar of the Community
Maineman750's Avatar
United States
3592 Posts
 Posted 12/17/2010  12:39 pm  Show Profile   Bookmark this reply Add Maineman750 to your friends list Get a Link to this Reply
I've seen PVC damage do that...not an expert,but passing on what I've seen.
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biokemist6's Avatar
United States
12437 Posts
 Posted 12/17/2010  12:42 pm  Show Profile   Bookmark this reply Add biokemist6 to your friends list Get a Link to this Reply
That color is almost certainly an indication of PVC residue and it should be removed ASAP. However, the damage may have already been done, especially on the Bicentennial Ike. Acetone will remove the residue, just make sure you thoroughly rinse the coins in fresh acetone after the soak.
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sel_69l's Avatar
Australia
21786 Posts
 Posted 12/17/2010  8:47 pm  Show Profile   Bookmark this reply Add sel_69l to your friends list Get a Link to this Reply
They have acquired a green tarnish from the leeching out of chloride compounds from the PVC, otherwise known as Polyvinyl Chloride.

The green cast is hydrous nickel chloride NiCl2.6H20. A lot of nickel compounds are green. If it is a coin of very low value, and forever will remain that way, keep it like that.

Green is my favourite colour!

Yay! This is my 600th post!
Edited by sel_69l
12/17/2010 8:49 pm
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BadThad's Avatar
United States
19930 Posts
 Posted 12/18/2010  01:23 am  Show Profile   Bookmark this reply Add BadThad to your friends list Get a Link to this Reply
Nice sel_691!

It's a combination of things. Oxidation and the reaction with chlorine in a slightly acidic environment (excessive exposure to air/humidity). It doesn't look like the classic PVC problem which usually looks like a green blob, similar to verdigris, but it's related. Hope this helps!
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Edited by BadThad
12/18/2010 01:28 am
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BadThad's Avatar
United States
19930 Posts
 Posted 12/18/2010  01:25 am  Show Profile   Bookmark this reply Add BadThad to your friends list Get a Link to this Reply
Note how nickel chloride looks in the spoon on the right side of the wiki page:

http://en.wikipedia.org/wiki/Nickel(II)_chloride

You have a thin layer.
Lincoln Cent Lover!
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Edited by BadThad
12/18/2010 01:27 am
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BadThad's Avatar
United States
19930 Posts
 Posted 12/18/2010  01:29 am  Show Profile   Bookmark this reply Add BadThad to your friends list Get a Link to this Reply
Nickel oxide is also greenish:

http://en.wikipedia.org/wiki/Nickel(II)_oxide
Lincoln Cent Lover!
VERDI-CARE™ INVENTOR
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BadThad's Avatar
United States
19930 Posts
 Posted 12/18/2010  01:30 am  Show Profile   Bookmark this reply Add BadThad to your friends list Get a Link to this Reply
I've never tried it, but a dip in an acid-thiourea solution would probably make them like new. Good practice coins!
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VERDI-CARE™ INVENTOR
https://verdi.care/
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