to check for genuine composition, below are properties of each type..
Years Type diam. wt (g) density (g/cm^3)
Gold Dollar
1849-1853 13.0 1.67 18.27
1854 Liberty Head 13.0 1.67 18.27
1854 Indian Head 15.0 1.67 18.27
1855-1889 15.0 1.67 18.27
Quarter Eagle
1796-1827 20.0 4.37 18.50
1829-1833 18.2 4.37 18.50
1834 Capped Bust 18.2 4.37 18.50
1834 Classic Head 18.2 4.18 18.33
1835-1836 18.2 4.18 18.33
1837-1839 18.2 4.18 18.27
1840-1929 18.0 4.18 18.27
Three Dollar Gold
1854-1889 20.5 5.02 18.27
Half Eagle
1795-1828 25.0 8.75 18.44
1829-1838 23.8 8.75 18.44
1839-1840 22.5 8.36 18.27
1840-1929 21.6 8.36 18.27
Eagle
1795-1804 33.0 17.50 18.50
1838-1932 27.0 16.72 18.27
Double Eagle
1850-1932 34.0 33.44 18.27
more subjective ways to identify a fake are feeling the weight of the coin (gold is MUCH heavier than other coins), color (gold takes centuries to tarnish, but the copper takes only a few years. particularly circulated coins, the color will have a antique-ish color to it. unc pieces may or may not have it.
other things to look for, no matter what the composition, are detail in the strike, accuracy and location of all the features. its best to know the coin. different years have variations in the dies, common flaws, etc.
or to save time, have NGC or PCGS do all that for you.