I don't know the specifics but they may be using any or all of size, weight, magnetic properties, electrical conductance, etc. They're already separating out copper pennies from plated under the ARP. A better question may be, would they bother?
im pretty sure they wouldnt bother sorting out the american pennies....but maybe there are alot of them. I have a huge jar of them from roll searching and iv even got rolls that are all american pennies or only 1 or 2 canadian ones mixed it.
I don't know if / how the laws can be applied outside of the United States, but it is a crime to melt US Pennies and Nickles. It is also a crime to export them to another country with the intent to melt them. I don't know how the rule applies to coins already in circulation in Canada, or if the Canadian government has / will have anything to say about it.
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