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Replies: 25 / Views: 9,631 |
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Moderator
 Canada
10458 Posts |
If you are a member of the RCNA, you can look up the paper I wrote with Rob Turner and Bill Hall on the 1859 brass cent. March 2012 issue.
"Discovery follows discovery, each both raising and answering questions, each ending a long search, and each providing the new instruments for a new search." -- J. Robert OppenheimerContent of this post is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported License. See: http://creativecommons.org/licenses...0/deed.en_USMy eBay store
Edited by SPP-Ottawa 05/27/2014 9:08 pm
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New Member
United States
1 Posts |
I am recently new member to this forum. I have a 1859 canada one cent I found when using metal detector and dug it up. I know nothing about it other than what ive read! Can someone please give me insight this coin is showing all signs of brass the metal detector says zinc and brass but I'm still not 100% convinced yet. I'm uploading pics maybe someone can help thanks.
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Pillar of the Community
Canada
1747 Posts |
Curious coin, the only true way to determine if that coin is brass is by having it tested using an XRF machine. this will x-ray the coin and determine the metals used. no one on this forum could tell you 100% it is brass with out this test.
I would recommend you finding a local coin shop and have them look at it, they may have one of these, or know where or who you can contact.
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Pillar of the Community
United States
1757 Posts |
Interesting thread so I will jump in knowing nothing of your coin, its issue and what its suppose to be or not be .... This coin appears to be brass based on its color. Interestingly when we see a brass coin turn green we have two possibilities in my opinion. As we increase the Zn level in brass (Cu/Zn) the color goes from copper/red light yellow (<10% Zn) to yellow (15-20% Zn) to greenish yellow (>25% Zn) - in general. The low Zn in Wood 14/15 Blacksmiths has created problems for years which is explained in my new book based on XRF results - not that any was really needed for you top end specialists. The other item that can make a brass coin turn green is a hot environment or as some people say someone maybe "fooling with it" chemically. Based on the greenish yellow color its almost certainly not bronze (Cu/Sn). In terms of weight be careful when you say all counterfeits weigh less ... not today particularly with modern Chinese forgeries which are made almost always to their proper regal weight - however I think this an environmentally (natural) altered brass piece - whatever that means for this later issue coin in this thread. My new book coming out shortly with over 1,000 coins analyzed by XRF will help in these matters since I devote an entire Chapter or almost 100 pages to the Canadian Blacksmiths and their XRF assays. Around May/June 2017 via Amazon Books. John Lorenzo United States
Edited by colonialjohn 03/01/2017 7:48 pm
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Pillar of the Community
 Canada
5589 Posts |
colonialjohn: What coin are you talking about... the one from a few years ago or the one from a few days ago? Were there pics uploaded to look at? If you look at the entry above in 2014, by SPP, I helped him with the XRF research that we did on the 1859 brass cents ... I am Bill. The "brass" 1859 cents constitute a verbal misnomer .. the '59 "brass cents were caused by an alloy mixing problem with the planchets. They were never meant to start out as brass cents ... the 95% copper, 4% tin and 1% zinc either stayed in the crucible too long and separated into semi-layers or was floating on top, before being poured into the small ingots. Some portion of the ingots then had a much higher zinc content so that, when the ingots were rolled into sheets, portions of the sheets alloyed out to be more like brass than the required bronze. There are over 25 different types or alloys of "brass", many of which have both zinc and tin in the alloy just like bronze. For our study on the 59's, we used the lowest copper content, highest zinc and lowest tin that could still be classified technically as brass.
From the well more than 500 1859's XRF'd, we found that the copper ranged from 90.9% to 95.98 and zinc ranged from 1.63 to 1.85. Needless to say, we found nothing that we could classify as brass, although we DID have access to the XRF or spectro stats on 2 coins that WERE classified as brass to serve as a target. In most of the XRF'd 1859's, there were traces of other elements ... iron, arsenic, lead, etc.
In your post from 1 March, you were talking about the visible "color" of the coins/tokens. From someone who had to shine many many brass cannons early on in my military life, I can tell you that the same brass cannon can change to many colors depending on what it comes in contact with, whether liquid or airborne. And from looking at 10's of thousands of 1859 cents, I can tell you that all kinds of colors are prevalent in them, depending upon which household cleaner that someone at some time used on them. You can turn the bronziest 1859 into the brassiest yellow you ever saw with a little 409 or spic & span or anything else under the sink. You can turn black to yellow in a heartbeat. Likewise you can can take a normal bronze cent out from the ground and have it appear "brassy" just from the alkaline content of the soil... XRF or spectro is the only way to tell the brass from the bronze.
I can't wait to get your book on the tokens, knowing that you have based your findings on actual XRF results, rather than "it looks like yellow". I had a couple of members of this site asking me to try to explain what you had in your post about "color". I think that many thought that they had or have had a brass '59 just because someone doused it with an oxidizing agent from any number of household cleaners at some time in its life.
Edited by okiecoiner 03/02/2017 04:50 am
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Pillar of the Community
United States
1757 Posts |
Okiecoiner - I find that UNUSUAL that the coin that started this thread (Marcuscoins - coin) is of the empirical alloy mix of: 95% copper, 4% tin and 1% zinc. You seem to suggest this in your first paragraph that possibly a large amount of zinc accidentally entered into this coin due to poor work practices at the Mint? Again I expect the Marcus piece to be very high Zn turning it yellow-ish green or a lower Zn say of a brass yellow alloy was oxidized in some manner (i.e., cleaned vigorously). See my previous post in this thread on color changes with increasing Zn levels. In terms of Canadian coins I only discuss XRF results of Blacksmiths and some associated tokens with this group. As with Mexico most people call something yellow = brass or reddish yellow = bronze. As you will see in my book there is brass, bronze, and brass/bronze alloys always as possibilities for many token issues. These XRF results allow us to draw some conclusions - some will be MINOR and others MAJOR (i.e., deleting certain varieties or more accurately moving them somewhere else such as to another time era and/or Country of origin).
JPL
Edited by colonialjohn 03/02/2017 11:06 am
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Pillar of the Community
Canada
1747 Posts |
Sorry guys, I was responding to Curious coins post, I wanted to give him a good idea of how to proceed to verify that his coin is brass or not.
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Pillar of the Community
 Canada
5589 Posts |
Colonial ... You can not tell that an 1859 Canada large cent is brass just by it's color. I have seen 100's of 1859's exactly the same color (or close to it) that were pure 95/4/1 bronze, heavy on the tin portion. All you need is some type of oxidizing agent, commonly found in household cleaners. to be used or applied to the coin and whammo ..you have brass yellow. We've gone through this drill 10's of times on these coin sites until they finally send it to a person with an XRF and Bingo ... bronze turned yellow by chemicals. The coin in question that started the thread has been heavily cleaned just by looking at its washed out appearance. I forget whether the original poster ever sent the coin to SPP to XRF, but it was nearly 3 years ago and NO "Eureka, look what I found" response.
I will repeat .. you can't tell a brass Vicky from a normal bronze one by looking at the color. In my post above, I didn't say that lots of zinc was added to the alloy, I said the improper mixing or agitation caused an increased zinc mixture to localize (whether the top or middle) so that the ingot or brick had some sections that were much more brass than bronze. When the ingots were rolled out into sheets/strips, those localized areas were cut into planchets just like everything else and the "brass" planchets were then delivered to the mint as part of the 10 million piece order. The planchets were actually made/manufactured at Heaton and then sent to the Mint to actually strike the coins. We'll just say that alloy composition and metallurgic practices were not real refined in the 1850's. I just don't want to put visions of sugarplums in young collector's heads by inferring that any 1859 Vicky that looks a little yellow, rather than chocolate brown, is an extremely rare brass one .. nothing can be further from the truth. The only way to tell is an XRF or spectro .. but a small scratch with a piece of glass on the edge, when viewed in sunlight, not indoors, will give a more positive clue than the external color of the coin. Please read the referenced Canadian Numismatic Journal article in SPP's post from 2014 about the 2012 article on the "brass" 1859 research project.
Edited by okiecoiner 03/02/2017 2:52 pm
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Moderator
 Canada
10458 Posts |
Quote: Okiecoiner - I find that UNUSUAL that the coin that started this thread (Marcuscoins - coin) is of the empirical alloy mix of: 95% copper, 4% tin and 1% zinc. I would bet my entire lunch on that the original coin in this thread is just a toned bronze. (Don't underestimate how much I value my lunch!!) I use a research-level XRF with my daily research, and having access to that instrument and a semi-quantitative SEM has been a fun experience with the 1859 cents. I also have collaborated with Chris Falkner on Upper and Lower Canada tokens... and I can pretty much say with confidence, that colour is NOT a reliable indicator of defining bronze versus brass... I am in the processing of writing a paper for the CN journal on this very topic, entitled "So you think you have an 1859 Brass Cent?" I had the pleasure of analyzing and photographing "yellow" 1859 coins that members and dealers alike had sent me over the years, with fingers crossed, only to learn they had a lovely yellow toned bronze cent....
"Discovery follows discovery, each both raising and answering questions, each ending a long search, and each providing the new instruments for a new search." -- J. Robert OppenheimerContent of this post is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported License. See: http://creativecommons.org/licenses...0/deed.en_USMy eBay store
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Pillar of the Community
United States
1757 Posts |
How can John Lorenzo argue with XRF - case closed. LOL.
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Replies: 25 / Views: 9,631 |