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Green Silver Coins?

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Author Previous TopicReplies: 15 / Views: 7,893Next Topic  
Pillar of the Community
Altaira's Avatar
Canada
2519 Posts
 Posted 10/31/2014  6:31 pm Show Profile   Bookmark this topic Add Altaira to your friends list Get a Link to this Message Number of Subscribers
Does anyone have an idea on what the green is, and can this coin be saved? Only one side is green and it's because this coin was at the end of a sellotape "roll". I don't even know how long it's been stored like that, but I can be certain it's at least 10 years.

Green-Silver-Coins?

I'm certain this isn't paint. There was one further down the roll that looks like it had been spray-painted orange.

Green-Silver-Coins?

Green-Silver-Coins?

Here's a closer shot, maybe you can see the texture of the green. (Also a few nice cracks, there's a big one running through DERL+INDIE:)

Green-Silver-Coins?

Green-Silver-Coins?

Anyone knows what this green is? I hope it's not corrosion.
Valued Member
Silver Handle's Avatar
United States
68 Posts
 Posted 10/31/2014  6:45 pm  Show Profile   Bookmark this reply Add Silver Handle to your friends list Get a Link to this Reply
What you have there is verdigris. Mostly occurring on copper and brass, but reacting with copper in coin. Here is a great tutorial :
http://www.ebay.com/gds/How-to-Remo...91989/g.html
Bedrock of the Community
sel_69l's Avatar
Australia
21786 Posts
 Posted 10/31/2014  7:03 pm  Show Profile   Bookmark this reply Add sel_69l to your friends list Get a Link to this Reply
These Indonesian quarter guilders have, if my memory serves me correctly, an alloy of .640 fine silver / copper.
They have been in a (chemically speaking), basic environment and the copper has preferentially surface corroded into a copper hydroxy carbonate, similar to verdigris.

I wouldn't worry too much about it though, because they are relatively common in EF conditon and found with mint luster. The Japanese effectively prevented their circulation during WW2, when they invaded Indonesia, thus they didn't circulate for long, if at all. They used to be found often in dealers' junk boxes in Sydney, and a lot of these coins found their way to Australia in soldiers' pockets.

VerdiCare may help with the cleaning of these quite well, because in this case, the surface layer of the 'green' would be quite shallow. The purity of the silver is sufficiently high enough to prevent deep corrosion of the copper component of the alloy.
Pillar of the Community
Altaira's Avatar
Canada
2519 Posts
 Posted 10/31/2014  11:45 pm  Show Profile   Bookmark this reply Add Altaira to your friends list Get a Link to this Reply
According to Krause in 1980 it is .720 silver.

They've been exposed to the humidity of Indonesia for so long, I had left this like this in my drawer in a wood shelf for almost 10 years (which is why I said at least 10 years in the sellotape).

If they're common I guess it's fine if I leave it as is for now. If it wasn't common I doubt I'll have a roll plus six more anyway. There are a few very nice blast white (but the rims have toned) ones in the middle.
Bedrock of the Community
sel_69l's Avatar
Australia
21786 Posts
 Posted 11/01/2014  01:21 am  Show Profile   Bookmark this reply Add sel_69l to your friends list Get a Link to this Reply
Pick out a half dozen of the best examples to keep for yourself.
Keep the rest for scrap silver coins, to be disposed of when you need a bit of extra money to buy something else.
Bedrock of the Community
United States
20753 Posts
 Posted 11/01/2014  11:10 am  Show Profile   Bookmark this reply Add just carl to your friends list Get a Link to this Reply
Why not just dip in Acetone? Or if not a valuable coin, Walmart Jewelry cleaner.
Pillar of the Community
Altaira's Avatar
Canada
2519 Posts
 Posted 11/01/2014  2:32 pm  Show Profile   Bookmark this reply Add Altaira to your friends list Get a Link to this Reply
I'm hoping to never sell these off though since it was from my grandma. The green doesn't look like what acetone can clean and I don't really want to ruin this coin either.

And I guess I need to brush up on my history, since sel knows more on Indonesian history than I do...
Pillar of the Community
Libertad's Avatar
Canada
3692 Posts
 Posted 11/01/2014  3:49 pm  Show Profile   Bookmark this reply Add Libertad to your friends list Get a Link to this Reply
The higher the copper content the higher the oxidation in silver alloys. It starts levelling off above 90% mix. This is why sterling silver (92.5% fine silver) is used for wearable pieces that touch your skin. Slip on a copper or brass ring and you'll see your skin turn green sometimes tinted blue. If you want to make a pendant from a coin you'll enjoy it more if it's .925 and higher.
Bedrock of the Community
BadThad's Avatar
United States
19947 Posts
 Posted 11/01/2014  10:17 pm  Show Profile   Bookmark this reply Add BadThad to your friends list Get a Link to this Reply
Verdigris, due to copper in the alloy.

The good news, it doesn't look to thick yet. The bad news, it appears to a very hard type of verdigris which can be quite difficult to remove. Since I've never seen these types of coins conserved, I don't even know how well VC will work.
Lincoln Cent Lover!
VERDI-CARE™ INVENTOR
https://verdi.care/
Bedrock of the Community
BadThad's Avatar
United States
19947 Posts
 Posted 11/01/2014  10:18 pm  Show Profile   Bookmark this reply Add BadThad to your friends list Get a Link to this Reply

Quote:
Why not just dip in Acetone? Or if not a valuable coin, Walmart Jewelry cleaner.


Carl, you know acetone won't touch verdigris. It would be an exercise in futility.
Lincoln Cent Lover!
VERDI-CARE™ INVENTOR
https://verdi.care/
Valued Member
magpie's Avatar
New Zealand
72 Posts
 Posted 11/02/2014  3:42 pm  Show Profile   Bookmark this reply Add magpie to your friends list Get a Link to this Reply
dull and very dirty silver coins I find here I use with CLR, not sure if you have that over there but it combats lime deposits etc. Works very well on silver coins I dig
Pillar of the Community
Altaira's Avatar
Canada
2519 Posts
 Posted 11/02/2014  3:48 pm  Show Profile   Bookmark this reply Add Altaira to your friends list Get a Link to this Reply
That's interesting Libertad, so that's why most silver jewellery I see are sterling.

I don't really want to be buying stuff online yet but if I find any VC locally I'll test it out.

I don't know what CLR is. If it works with lime deposits I assume it's acid?
Valued Member
magpie's Avatar
New Zealand
72 Posts
 Posted 11/02/2014  3:57 pm  Show Profile   Bookmark this reply Add magpie to your friends list Get a Link to this Reply
I think it might be? its not a strong acid if it one. It comes in a plastic bottle, CLR stands for Calcium, Lime and Rust. I've got it on my hands plenty of times and never got any irritations but I wouldn't recommend doing that.
Pillar of the Community
Altaira's Avatar
Canada
2519 Posts
 Posted 11/02/2014  4:00 pm  Show Profile   Bookmark this reply Add Altaira to your friends list Get a Link to this Reply
From what it stands for I'm even more convinced it's acid, but I'm just guessing here, I've never heard of CLR before.
Bedrock of the Community
BadThad's Avatar
United States
19947 Posts
 Posted 11/02/2014  7:07 pm  Show Profile   Bookmark this reply Add BadThad to your friends list Get a Link to this Reply

Quote:
From what it stands for I'm even more convinced it's acid, but I'm just guessing here, I've never heard of CLR before.


Yes, it is a solution of a couple different organic acids, primarily lactic acid.

Using anything acidic on coins will permanently damage the surfaces. Acids and metals do not get along nicely. If you use acid on a coin, it will come out dull and lifeless.

The application of a harsh cleaning to a coin is best done on the basic side of the pH scale. Sodium hydroxide (lye) is a better choice but it will still cause some havoc.
Lincoln Cent Lover!
VERDI-CARE™ INVENTOR
https://verdi.care/
Valued Member
magpie's Avatar
New Zealand
72 Posts
 Posted 11/02/2014  11:37 pm  Show Profile   Bookmark this reply Add magpie to your friends list Get a Link to this Reply
I will keep that in mind if I come across anything rare. I am not too worried about my detected coins, we don't have anything rare over here and I have no intentions of ever selling them, took much to much effort to find them!
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