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Found PVC Residue On Old Coins

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Cheyenne's Avatar
United States
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 Posted 06/18/2018  7:48 pm Show Profile   Bookmark this topic Add Cheyenne to your friends list Get a Link to this Message Number of Subscribers
Well, I was completely unaware of PVC residue and the damage it can cause to coins. Most of my old collection is in 35-40 year old Whitman books I filled as a kid. Those are currently MIA, but I know they're in my house somewhere along with a handful of coins in flips...ugh.

I did find a 1923 Peace dollar I bought 25 years ago (was still residing in the same flip) has picked up that milky coating in spots. My wife and I also have an old (30+ years) old vinyl zipper bag that her grandfather had stored about 10 Peace and Morgan dollars (loose in the bag). Most of these are worn, and most are very discolored, ranging from black to varying shades/streaks of green. They look pretty bad. I'm going to look up acetone dipping and see if the PVC can be removed, though I'm sure the coins have little value beyond melt. Mainly, we'd like to keep them as they were her grandfather's who passed back in 1993. She was very close with him, and of course, wants to keep his coins. Until I recently started reading coin forums like CCF, I had no idea those little plastic flips could damage a coin!

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Errers and Varietys's Avatar
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 Posted 06/18/2018  10:38 pm  Show Profile   Bookmark this reply Add Errers and Varietys to your friends list Get a Link to this Reply
Same here. I didn't know, until I joined this forum. If Acetone doesn't work,try Verdi-Care.
Errers and Varietys.
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sel_69l's Avatar
Australia
21786 Posts
 Posted 06/19/2018  12:17 am  Show Profile   Bookmark this reply Add sel_69l to your friends list Get a Link to this Reply
I agree that the acetone and Verdi-Care track would be a good way to go.

It is the oily softener in clear PVC that causes problems, not the chloride. The softener slowly gasses out, directly onto the coin. Over a period of ten years or more, the coins can darken considerably. Complex organic / inorganic metallic compounds form a film on the coin in a sort of patina. Some of these compounds form part of that patina, and some of them can be dissolved and removed with acetone.

Verd-Care does its stuff by working on complex metallic double salts (hydroxycarbonates) in the film on the surface coin. Does not work very well on coins that have hardened vewrdigris lumps, which underneath them, have pitted the surface of the coin. Irreversible damage, it that is the case.

In future, house your coins and notes in non PVC (polypropylene or mylar) album pages.
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spru's Avatar
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 Posted 06/19/2018  01:57 am  Show Profile   Check spru's eBay Listings Bookmark this reply Add spru to your friends list Get a Link to this Reply
with the above. Remaining PVC residue can be easily removed with pure acetone. Sometimes, however, it has already affected the coin's surface detrimentally. In any case, acetone is the way to go and you get what you get in the end. Some may step up to xylene, but if the residue has done damage, that's permanent and no treatment will make it better.

Aside purchasing coin-specific storage solutions, remember that any Ziploc bag or container that is "Food Safe" is also PVC-free and perfectly fine for coins.
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T-BOP's Avatar
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 Posted 06/19/2018  07:29 am  Show Profile   Bookmark this reply Add T-BOP to your friends list Get a Link to this Reply
In almost all cases a soak in acetone followed by an application of Verdi-Care will greatly improve any verdigris problem . Some might be tougher than others .
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 Posted 06/20/2018  08:17 am  Show Profile   Bookmark this reply Add just carl to your friends list Get a Link to this Reply
And to this web site.
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Cheyenne's Avatar
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 Posted 06/21/2018  2:31 pm  Show Profile   Bookmark this reply Add Cheyenne to your friends list Get a Link to this Reply
Thanks for the replies. Going to try out the pure acetone this evening. I'll try to post a few before/after pics if I can manage!
Edited by Cheyenne
06/21/2018 2:32 pm
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Cheyenne's Avatar
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 Posted 06/25/2018  4:08 pm  Show Profile   Bookmark this reply Add Cheyenne to your friends list Get a Link to this Reply
One before and after acetone treatment for PVC residue on Peace dollar. The coins are far from perfect, but do look better.

Before: https://photos.app.(Offsite URL shortening not allowed-G) /uuU8kWpQSv1zL42N8
https://photos.app.(Offsite URL shortening not allowed-G) /N7BotTV7nXdkpYzQ6

After: https://photos.app.(Offsite URL shortening not allowed-G) /VQPtamycmCoiR3ic6
https://photos.app.(Offsite URL shortening not allowed-G) /h7ZP2m2nGRTr56cVA[/img]

Ah, well, no pics...
They are on google photos...
Edited by Cheyenne
06/25/2018 4:20 pm
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Conder101's Avatar
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 Posted 06/25/2018  8:04 pm  Show Profile   Bookmark this reply Add Conder101 to your friends list Get a Link to this Reply

Quote:
In almost all cases a soak in acetone followed by an application of Verdi-Care will greatly improve any verdigris problem .

Acetone will not do anything to verdigris other than dry the moisture out of it, which will help keep it from progressing as long as it is then kept dry. It will not remove it. Too many newbies hear us talking about acetone and they seem to get the idea it is some miracle chemical that will clean, remove toning, maybe even restore mint luster. Nope it is just a "degreaser" and drying agent that won't react with the metal or toning.
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 Posted 06/26/2018  02:05 am  Show Profile   Check spru's eBay Listings Bookmark this reply Add spru to your friends list Get a Link to this Reply
In Memory of Crazyb0 12-26-1951 to 7-27-2020
In Memory of Tootallious 3-31-1964 to 4-15-2020
In Memory of T-BOP 10-12-1949 to 1-19-2024
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Dorado's Avatar
Canada
24885 Posts
 Posted 06/26/2018  08:55 am  Show Profile   Bookmark this reply Add Dorado to your friends list Get a Link to this Reply

Quote:
Ah, well, no pics...


Here is the tutorial about uploading and posting images

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And here is the CCF Free Image Optimizer to help crop your images.
https://www.coincommunity.com/image-optimizer/

Please preview your post/pictures to be sure they are rotated correctly.

(By FUZZY317)
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