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Replies: 9 / Views: 6,576 |
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Pillar of the Community
 United States
2448 Posts |
Recently read an article concerning the petina copper and bronze takes on with time. In another thread, someone alluded that it can be treated. Same person suggested that it is contagous. It this the same green, mold like substance I view under my microscope? I thought it was inevitable; as an example the Statue of Liberty. Should it be treated and with what?
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Pillar of the Community
United States
1534 Posts |
Most likely, yes. Contact BadThad, he's developed a product to treat verdigris. The product name is Verdi-Gone.
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Pillar of the Community
United States
2661 Posts |
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Bedrock of the Community
United States
20753 Posts |
Quote:
Recently read an article concerning the petina copper and bronze takes on with time. In another thread, someone alluded that it can be treated. Same person suggested that it is contagous. It this the same green, mold like substance I view under my microscope? I thought it was inevitable; as an example the Statue of Liberty. Should it be treated and with what?
Bronse and Brass are simply mixtures of Copper and other substances. It's basically the Copper that takes on the so called Patina. Usually, not always, Copper simply combines with Oxygen to form a darker coating with time and sufficient exposure. If the Patina appears to be starting to turn greenish, most likely just more exposure to Carbon Dioxide, moisture and Oxygen. Statues and other items should really have been coated with something to stop such exposures. Copper types of piping around homes usually acquires such Patina and could be stopped by simply coating with a clear high temp Laquer. UNFORTUNATELY this is not a good idea for coins. The best thing for such coins is preverntive measures. In other words attempt to not allow coins to get exposed to the so called elements. However, once started, if someone wants to spend a small sum, the advise to try Thad's solution would be worth a try. As to contagious. Don't see how since it is not alive, movable or is it? 
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Bedrock of the Community
United States
19935 Posts |
Quote: Recently read an article concerning the petina copper and bronze takes on with time. In another thread, someone alluded that it can be treated. Same person suggested that it is contagous. It this the same green, mold like substance I view under my microscope? I thought it was inevitable; as an example the Statue of Liberty. Should it be treated and with what? Yes, verdigris can be removed by several different means. However, most of them end up damaging the surface. My current product, VERDI-CARE™, is able to remove light to moderate verdigris without strippng the surface. Verdigris is absolutely able to spread. Please see my response in this thread: https://goccf.com/t/68881
Lincoln Cent Lover!VERDI-CARE™ INVENTOR https://verdi.care/
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Bedrock of the Community
United States
19935 Posts |
Quote: The product name is Verdi-Gone. My newest product is called VERDI-CARE™. VERDI-GONE is being discontinued.
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Pillar of the Community
  United States
2448 Posts |
Well, I'm not quite sure how to respond to use of the product. In my experience with metals whether any of the tungsten/moly tempered steels, copper, aluminum, of base iron, the common problem for all (except mercury) is corrosion. (If you're thinking of anodized and chromed steel, go to any junk yard and check out the old cars.) Wish I had a Mercury dime for each time I looked at a machined part (whether forged, extruded, or milled) displaying plastic/permanent deformation, or failure from fair wear & tear initiated by corrosion. We collectors are stuck between cleaning and not cleaning (or if you prefer "conserving") our coins when presented with particular problems. Oxidation of copper or any copper alloy is the patina we see under our microscopes and call Verdigris. If, since as reported, the coin is "damaged" when treated, is it wise to even pursue a cure? In several threads in the community, I've seen members offer remedies to members with "problem" coins up to and including "Ketchup". (Now don't think this is the only place that has offered that solution; it's been suggested on other sites also.) While I believe that no action is the appropriate action, I'm certainly open for suggestions especially since I'll never sell my real collection; my heirs will have to fight that battle. I'm thinking the presence of Verdigris helps to prove the coin has not been cleaned. In my original ROI, I probably should have qualified my request with the phrase: "and not be considered cleaned". Not withstanding further discussion, is there a site or example of the results of this treatment? Can the treatment be readily detected? Since some damage occurs, does it leave clear patchy areas on the coin typical of cleaned copper? I know that the only way to prevent or halt the corrosion or oxidation of metal is storage in a vacuum or an atmosphere of non-degrading noble gas. (BTW, we're even learning that there is also corrosion in outer space.) Since, here on earth, all nature abhors a vacuum, oxygen will eventually make it into our container. Several thousand of years from now, no one will care. (Well unless you're in the middle of a farmers field with a metal detector and then it becomes a hoard.) Thanks BadThad for the info. 
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Bedrock of the Community
United States
20753 Posts |
carmykie: For clarification your partially correct that the STUFF seen on coins as a patina, discoloration, so called Verdigris, corrosion, etc is in reality a combination of the coin and other outside substances. Usually moisture, Oxygen, Carbon Dioxide and numerous others. This combination of the coins metal when removed takes some of the metal with it. In most instances a decent collector can notice this as a cleaned coin but in many other instances such minor touchups are difficult to detect. I've experimented cleaning coins for many, many years and then showed them to so called experts at coin shows. As an overall experience any types of cleanings have been detectable, however, in some instances people would swear the coin has never been cleaned in any way at all. My suggestion is if you want to try, try Thad's stuff, or the many possible items you would find listed in the Search tab for cleaning coins, coin cleaning, Actone, etc. It's amazing how you will find people that claim they've cleaned coins with Olive Oil, Lighter fluids, Acetone, Tomato Juice, Lemon Juice, nuclear reactors, Acids of all types, Vinegar, Kerosine and on and on and on and on. My preference is to simply burn off any contaminates with a Butane Torch.  
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Bedrock of the Community
United States
19935 Posts |
Quote: Oxidation of copper or any copper alloy is the patina we see under our microscopes and call Verdigris. If, since as reported, the coin is "damaged" when treated, is it wise to even pursue a cure?
The oxidation of copper is not the same as verdigris. Verdigris is when copper combines with chemical anions. The oxidation of copper forms copper oxides. Right after being minted a layer of Cu2O, cuprous oxide, forms on the surface. This is actually a nice protective layer. As the layer thickens, the copper will become a deeper red color. With excessive exposure to oxygen and heat, cupric oxide can form (it's black). From my book to save typing: Quote: In the absence of corrosive ions and acidic or basic conditions, copper oxide will last virtually forever. Unfortunately for the numismatist, the layer tends to become more oxidized and a bit thicker with time. This will darken the coin as the ratio of cupric oxide to cuprous oxide increases. A very heavily oxidized copper coin can become black. Verdigris happens when copper is converted to copper hydroxide via exposure to air and water. The highly reactive copper ions then combine with anions like formate, acetate, sulfate, chloride, etc. The key to conservation is the degree of the vergris. I classify verdigris into three types: light, moderate and heavy. In the case of the first two types, very few copper atoms are removed from the surface. Conservation usual leaves behind almost no trace of evidence, especially with light verdigris, because so little copper has been removed. However, with heavy verdigris, there will be definite pits left behind, so a coin with this type of verdigris is generally not worth conserving. So, to answer your question, YES, light to moderate verdigris is definitely worth conserving. Quote: I'm thinking the presence of Verdigris helps to prove the coin has not been cleaned.
No it doesn't, it could also mean that someone just didn't get aggressive enough to remove it. I've seen TONS of coins where people tried to remove verdgirs, but left a lot behind. Quote: In my original ROI, I probably should have qualified my request with the phrase: "and not be considered cleaned". Not withstanding further discussion, is there a site or example of the results of this treatment? Can the treatment be readily detected? Since some damage occurs, does it leave clear patchy areas on the coin typical of cleaned copper?
All you have to do is scroll down in the main forum. LOL https://goccf.com/t/62434Most of your questions should be answered after reading that. If you still have more questions, please feel free to ask. You're motivating me to get back to work on my book. It's mostly done, just a few final touches and it will be ready. It's going to answer every question a collector could have about copper coin verdigris.
Lincoln Cent Lover!VERDI-CARE™ INVENTOR https://verdi.care/
Edited by BadThad 07/24/2010 12:44 pm
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Pillar of the Community
  United States
2448 Posts |
Great Bad Thad! Let me know when it comes out! However, I only buy signed first editions! BTW, don't forget to include info on contaminated metals in blanchets. ( Sometimes it happens and not even a blowtorch can cure em.)Thanks for the additional info! You too just carl. 
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Replies: 9 / Views: 6,576 |
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