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1984-D Zinc Rot Oddity

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Drav3n's Avatar
United States
28 Posts
 Posted 06/03/2013  04:17 am Show Profile   Bookmark this topic Add Drav3n to your friends list Get a Link to this Message Number of Subscribers
Just wanted to get some input on this coin. Found it quite odd, as how obvious the damage was even to the naked eye. I am quite well aware of the zinc rot taking place around the bottom of the mint mark. But look around it as the area around the mint mark is completely raised. I want to see if my assumption could be correct. Possibly grease buildup around a cracked/broken die or a chip that became so great that it created a raised mound around the mint mark? Thus creating a weak area allowing zinc rot to set in? I just found it neat and thought I would get some input and feedback from the community.

1984-D-Zinc-Rot-Oddity
Pillar of the Community
United States
1915 Posts
 Posted 06/03/2013  04:40 am  Show Profile   Bookmark this reply Add seal006 to your friends list Get a Link to this Reply
Most likely the raised area is just from the plating bubbling up. As the zinc rots it expels a gas. The copper plating layer is very thin and pliable. As the gas is released it causes the copper layer to rise.
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Drav3n's Avatar
United States
28 Posts
 Posted 06/03/2013  05:04 am  Show Profile   Bookmark this reply Add Drav3n to your friends list Get a Link to this Reply
Makes sense, thank you. I did not think about possible fumes or gasses being released but if a chemical reaction is taking place then certainly some by-product is expelled as a result of the reaction. Heat, if nothing else.Thank you.
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Conder101's Avatar
United States
17884 Posts
 Posted 06/03/2013  2:01 pm  Show Profile   Bookmark this reply Add Conder101 to your friends list Get a Link to this Reply
During the strike the plating splits by the mintmark alowing water and air to get it. This leads to "zinc rot" or corrosion as the zinc combines with the air and water to create zinc oxide. Zinc like iron spalls as it corrodes, the corrosion products puffing up and flaking off as it corrodes. The problem here is corroding zinc is held in place by the plating so it swells up creating the bulging areas under the plating. Have you ever seen a car rusting under the paint job where the rust hasn't broken through to the surface? You see the same type of bulges under the paint. then one day it breaks through the the rust starts flaking away.
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