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Refining Gold With Acid?

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Jaobler's Avatar
United States
6394 Posts
 Posted 07/28/2011  1:22 pm  Show Profile   Bookmark this reply Add Jaobler to your friends list Get a Link to this Reply
I haven't tried it myself but I expect you can reclaim gold from lower-karat alloys using NITRIC (not Hydrochloric) acid. That would dissolve silver, copper, and most other common components without touching the gold. The jewelry piece should disintegrate as the non-gold components dissolve, leaving a finely-divided gold residue.

I agree if you use hydrochloric acid you will have a potential problem with silver chloride mixed in. Silver chloride however is readily soluble in Ammonium Hydroxide (NH4OH) solution which might give you a viable option for removing that contaminant. The silver-ammonia complex is an intense dark blue color which gives an immediate indication about whether silver chloride is present.

When I sold some of my refined gold years ago the purchaser charged me $30 to have it assayed, then paid me based on the actual gold weight. Any reputable gold buyer should have access to low-cost assay services.

Back then I worked in a lab and was able to use atomic absorption spectroscopy to assay my gold. The result was consistently about 99.9% which was the resolution limit of the equipment. That gave me some confidence about the reliability of the refining process.

Interesting discussion!
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Ed_B's Avatar
United States
4008 Posts
 Posted 07/28/2011  8:50 pm  Show Profile   Bookmark this reply Add Ed_B to your friends list Get a Link to this Reply

Quote:
In Western Australia, gold is mined in the mineral telluride, which is also a complex gold double salt in association with tellurium. Again, I do not know if this mineral is soluble or not. I guess that gold is recovered from telluride by the simple application of heat.

I have no experience with material of that type, so cannot advise anyone of how it should be handled. Search the Internet for gold refining processes to see what the usual industrial purification methods are. If various ores are mentioned, they should have different purification processes.

Many complexes can be broken down by heating them strongly. Most often, this results in the ejection of small molecules, such as water, ammonia, or H2S. Note that H2S has considerable toxicity and that an early symptom of H2S poisoning is euphoria and a loss of cognitive capacity... a VERY dangerous combination.


Quote:
How fine must the gold alloy particles have to be?

How high is the sky? Questions like this don't have a direct answer and depend on the purity level you are trying to reach. The smaller the particle, the higher the surface area, and the greater the removal of surface impurities will be. The ultimate in this is, of course, when the gold is completely dissolved and exists in solution as a gold molecular complex of some kind.


Quote:
I suppose pH management would control this preference.

Yes, good pH control would be necessary to maintain the amount of acid available for impurity extraction and solution. A way of adding fresh acid to the mixture as the purification process completed would also be needed. This can be a tricky step, as acid additions will result in different pH changes depending on how quickly the acid is consumed. Good mixing of such solutions is critical so that pools of highly concentrated acid do not float around in the solution but are quickly dispersed throughout the solution. A homogeneous or nearly homogeneous solution should work the best but maintaining that homogeneity during the purification process can be tricky.

Various catalysts are produced for the chemical industry by making an alloy of, say, nickel with aluminum. This is made in blocks that are then milled to a specific granule size. An aqueous solution of NaOH is then added to a stirring slurry of the catalyst granules. The caustic soda leaches out some of the aluminum, creating a "sponge nickel" catalyst. These can be "hot", in that they are so reactive, they will sometimes burst into flame when allowed to dry out in the presence of air. While this process is done on purpose to generate a particular catalyst, the effect that occurs during its manufacture could be similar to what you would achieve with your gold purification. Not that any gold sponge that results would likely be pyrophoric, of course.
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