I won't dismiss the possibility that it could be
Struck Through Grease smear (more likely), or rusty dies (less likely), but I am not completely opposed to the above opinions, either.
Need to look at this one in hand with a 10x loupe, to form a more exact idea.
To my eye acid attack seems less likely, due to the very circular shape of the affected area. Not heat; it would be considerably more darkened than it actually appears to be.