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What To Do After A Bath In Water/Acetone?

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joe_77's Avatar
Italy
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 Posted 01/02/2024  4:06 pm Show Profile   Bookmark this topic Add joe_77 to your friends list Get a Link to this Message Number of Subscribers
Hello everyone & thank you for having me!

As I'm trying to develop some experience in handling and conserving old coins as an amateur, I came across a number of excellent topics from this community such as:
Copper Coin Conservation The Correct Way - http://goccf.com/t/404457
Black Gunk.. - http://goccf.com/t/57008

I really like the method presented by BadThad as the "Polarity Ladder". The idea of alternating (back and forth) water and acetone (leaving aside the strongest step of the ladder for now) seems safe enough and I'm considering trying it on some cheap copper coins. At the end of the day it seems water and acetone are the basis for professional conservation as well (as an interesting side note, I found detailed description of conservations steps on the website of the British Museum (like https://www.britishmuseum.org/colle...term/60466:1 -- searching for keywords such as "treatment" and the metal or substance you are interested in yielded a lot of interesting examples).

However, I'm not clear yet on a crucial aspect: what to do after a bath?

More specifically, imagine I bath for 30 mins a coin in water (distilled).
How am I supposed to handle the coin afterwards?
Ordering perhaps from less to more intrusive:
Is "swirling" it inside the old or new water the best approach? obviously while holding it so it doesn't bang on the container! [note: assuming the old water is now full of dissolved gunk or debris might be better use clean one]
Or using a soft cotton ball/swab gently pressing (no rubbing)?
Or how about using one of those magnetic stirrer to create a kind of gentle washing machine effect (obviously the coin will need to be suspended so that it won't touch any surfaces) for some minutes?
Or with soft bristles brush be fine? Few gentle strokes per side obviously
Or something else I am missing or a combination of the above?

Thank you very much for your guidance!

Have a great day
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John1's Avatar
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 Posted 01/02/2024  4:09 pm  Show Profile   Bookmark this reply Add John1 to your friends list Get a Link to this Reply
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jbuck's Avatar
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 Posted 01/02/2024  4:26 pm  Show Profile   Bookmark this reply Add jbuck to your friends list Get a Link to this Reply
to the Community!

Always use a flowing rinse of clean acetone when you are done. Allow it to air dry.
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Coinfrog's Avatar
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 Posted 01/02/2024  5:07 pm  Show Profile   Bookmark this reply Add Coinfrog to your friends list Get a Link to this Reply
Don't overthink it.



to the CCF!
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sel_69l's Avatar
Australia
21786 Posts
 Posted 01/02/2024  8:54 pm  Show Profile   Bookmark this reply Add sel_69l to your friends list Get a Link to this Reply
Look at lots of videos on how museums conserve / restore their coins.

Different coins from different previous environmental conditions require different c/r methods.

Having made these two comments, almost all coins require no treatment at all.

Buy right in the first place, and most of the c/r problems are avoided.
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sel_69l's Avatar
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 Posted 01/02/2024  9:08 pm  Show Profile   Bookmark this reply Add sel_69l to your friends list Get a Link to this Reply
Beautiful rainbow toned coins need preservation.
Best way to do that is a quick soak in acetone, let dry and seal in an airtight positive screw seal capsule.

My only problem with rainbow toned coins from what I can best determine is that
most of them have acquired their toning by artificial means,
and as such, should not have any more value over their equivalents without any toning.
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Sap's Avatar
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 Posted 01/02/2024  10:10 pm  Show Profile   Bookmark this reply Add Sap to your friends list Get a Link to this Reply
If you're going to be soaking a coin in water, then you'll need to dry it off before soaking it in anything else. If you've got acetone and were going to be doing multiple dips in acetone anyway (this is recommended), then the first dip in acetone could be considered "drying" - buy you'd still want to get rid of as much water as possible before putting it in the acetone.

Acetone evaporates away quickly. You do not need to do anything to a coin after an final acetone rinse.

As for any treatment of the coin while it is submerged, I would not recommend rubbing or scrubbing, with anything. I would recommend using an eyedropper or plastic disposable pasteur pipette to squirt jets of solvent onto stubborn areas of goo, while the coin is submerged. I use something like these, but that's just because we've got boxes of them sitting around the lab where I work.
Don't say "infinitely" when you mean "very"; otherwise, you'll have no word left when you want to talk about something really infinite. - C. S. Lewis
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tdziemia's Avatar
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 Posted 01/02/2024  10:21 pm  Show Profile   Bookmark this reply Add tdziemia to your friends list Get a Link to this Reply
Lots of lotion since the acetone tends to dehydrate the skin.
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joe_77's Avatar
Italy
284 Posts
 Posted 01/03/2024  06:57 am  Show Profile   Bookmark this reply Add joe_77 to your friends list Get a Link to this Reply
Thanks all for the welcoming and pointers!


Quote:
Don't overthink it.

Ahah, as I'm a serial overthinker, it's like asking water not to be wet


Quote:
Look at lots of videos on how museums conserve / restore their coins.

Any examples that come to mind? I couldn't find any video specifically from museums but probbaly I missed them. Most of the video starts with good intentions but inevitably end up bring out the old toothbrush!


Quote:
Buy right in the first place, and most of the c/r problems are avoided.

My primary interest as of now is to conserve/preserve the thousands of -- very dirty -- coins passed down in my family. Probably 90% of them are common ones but hold sentimental value nonetheless.
Nevertheless I still want to try doing the best job I can (plus it's always nice to learn a new skill!)

Just to give an example, this is a detail of a copper coin which just had its 100th birthday -- minted in 1924 (this is an Italian 5 cents, nicknamed "wheat spikes"). Would you all consider this a coin that would benefit from a proper conservation treatment as opposed to spending the next 100 years as is?

What-To-Do-After-A-Bath-In-Water/Acetone?
What-To-Do-After-A-Bath-In-Water/Acetone?

What I'm reading so far seems to indicate that water and acetone baths will require different techniques.

With distilled water all is easier (can use bigger jars, more liquid), just swirling to coin held with my fingers on the rims should serve the purpose of "rinsing it".

With acetone I'll probably use small containers so a squirting pipette after the bath will do the trick.

Thanks a lot to all!
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tdziemia's Avatar
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 Posted 01/03/2024  08:50 am  Show Profile   Bookmark this reply Add tdziemia to your friends list Get a Link to this Reply
Best wishes for your efforts.

If the green areas are copper salts, neither water nor acetone is likely to help, but they also will not hurt.
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Sharks's Avatar
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 Posted 01/03/2024  1:39 pm  Show Profile   Bookmark this reply Add Sharks to your friends list Get a Link to this Reply
joe_77
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Sap's Avatar
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 Posted 01/03/2024  4:59 pm  Show Profile   Bookmark this reply Add Sap to your friends list Get a Link to this Reply
Once a copper or bronze coin starts to turn green, there's really nothing that can be done to help it; anything done to the coin to take the corrosion away will only make it look worse.

I am slightly worried about this particular coin; the pale green dusty appearance of the corrosion could be the beginning of bronze disease, an "infections" form of corrosion that can spread to cover not just this coin, but any other copper or bronze coin it touches, or on which pieces of the green dust break off and land on.

Acetone will not really help bronze disease, and water will only make it worse.It needs stronger chemicals.
Don't say "infinitely" when you mean "very"; otherwise, you'll have no word left when you want to talk about something really infinite. - C. S. Lewis
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hfjacinto's Avatar
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 Posted 01/03/2024  8:42 pm  Show Profile   Bookmark this reply Add hfjacinto to your friends list Get a Link to this Reply
You need verdicare for that coin, acetone and water won't do anything. That coin needs a long soak and some mechanical movement (like with a toothpick) to remove that.
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joe_77's Avatar
Italy
284 Posts
 Posted 01/04/2024  11:59 am  Show Profile   Bookmark this reply Add joe_77 to your friends list Get a Link to this Reply
Thanks to all for the additional pointers provided!

A couple of questions: assuming verdigris is present on the coin, will the correct procedure be: water then acetone then something else/mechanics removal of the verdigris (and then water and/or acetone again)? Or should the verdigris be addressed first? In the above comments it was written that water will make it worse but also that it wont hurt.

Verdicare, Verdigone, etc seem to be USA products. I read about EDTA (either localised or in full immersion) or Sodium Sesquicarbonate (bath), anyone has experience with these?

If I seal the coin (with for example Paraloid), will verdigris reappeared if removed or will it spread if left untouched?

Thanks a lot!

EDIT: regarding verdigris and procedure with other baths I found an old writing by BadThad stating how a distilled water + baking soda would help before treatment to neutralise the acids on the coin.
I wonder if for copper coins would be best to follow this procedure:
1. Distilled water baths + sodium bicarbonate (few) cycles. Purpose: neutralise acids and remove water soluble gunk
2. Acetone baths cycles. Purpose: remove acetone soluble gunk
3. Verdigris treatment. Purpose: stop (and removing oxides depending on treatment) the verdigris reaction
4. Distiller water baths. Purpose: remove water soluble gunk which was under acetone soluble gunk and remove salts/chemicals deposited in step 1 or 3
5. Acetone rinse. Purpose: drying the coin
6. Applying sealant

What do you all think?

By the way, just to make a list of them, so far the Verdigris treatment I found are:
mechanical or questionable as far as conservation safe (e.g. lemon juice)
verdicare or verdigone specific products
EDTA bath or localised treatment
Sodium Sesquicarbonate (water, sodium bicarbonate and sodium carbonate) bath
Edited by joe_77
01/04/2024 3:31 pm
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Chute72's Avatar
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 Posted 01/10/2024  4:59 pm  Show Profile   Bookmark this reply Add Chute72 to your friends list Get a Link to this Reply
Good things are possible with patience.


What-To-Do-After-A-Bath-In-Water/Acetone?


What-To-Do-After-A-Bath-In-Water/Acetone?


What-To-Do-After-A-Bath-In-Water/Acetone?
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jbuck's Avatar
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 Posted 01/10/2024  5:07 pm  Show Profile   Bookmark this reply Add jbuck to your friends list Get a Link to this Reply

Quote:
Good things are possible with patience.
Looking good!
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