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Storing Silver Coins In Titanium

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exodus125's Avatar
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 Posted 04/08/2010  10:01 am Show Profile   Bookmark this topic Add exodus125 to your friends list Get a Link to this Message Number of Subscribers
I was wondering if anyone knows if silver would have any weird reaction to titanium, if its stored inside a titanium tube.
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fioti's Avatar
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 Posted 04/08/2010  11:13 am  Show Profile   Bookmark this reply Add fioti to your friends list Get a Link to this Reply
I've seen titanium/silver rings for sale on da bay. So maybe it's o.k. What connections do you have to get the tubes? Check & see if they are China made. Their titanium is cheaper, most often containing impurities, so I've heard.
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BadThad's Avatar
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 Posted 04/08/2010  11:14 am  Show Profile   Bookmark this reply Add BadThad to your friends list Get a Link to this Reply
Never mix metals! There's always a chance of galvanic corrosion. Use plastic, it's the best choice for coin storage.
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exodus125's Avatar
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 Posted 04/08/2010  11:17 am  Show Profile   Bookmark this reply Add exodus125 to your friends list Get a Link to this Reply
I actually work with the stuff. With my recent coin collecting of silver coins, I was thinking about getting some of those plastic tubes to keep my silver quarters in, but I figured I could easily make a cool one out of titanium. I just dont know if it will cause any weird reactions to the silver.
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exodus125's Avatar
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 Posted 04/08/2010  11:22 am  Show Profile   Bookmark this reply Add exodus125 to your friends list Get a Link to this Reply
there you go. Will have to google that galvanic corrosion. Thanks for that.
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Tim Stroud's Avatar
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 Posted 04/08/2010  11:25 am  Show Profile   Bookmark this reply Add Tim Stroud to your friends list Get a Link to this Reply
with BadThad. Though both metals are in the cathodic range as far as electrode potential, Silver has a higher EP (+.799) than Titanium (+.055). Thus the Titanium would cause the silver to corrode or tarnish unless you are able to obtain and maintain a 0% humidity level within the tube. You would in effect be creating a very low voltage battery that would use the Silver as a sacrificial metal.
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southerngent's Avatar
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 Posted 04/08/2010  11:27 am  Show Profile   Bookmark this reply Add southerngent to your friends list Get a Link to this Reply
You can always make the titanium an outer sleeve and keep the plastic inner sleeve. It would still look very cool and be safe. Just a thought.
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exodus125's Avatar
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 Posted 04/08/2010  11:28 am  Show Profile   Bookmark this reply Add exodus125 to your friends list Get a Link to this Reply
I should acid clean an old dime and store it inside and see what happens. How long would it take for the tarnishing or corroding to take place you think?
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exodus125's Avatar
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 Posted 04/08/2010  11:29 am  Show Profile   Bookmark this reply Add exodus125 to your friends list Get a Link to this Reply
southerngent, thats a good idea!
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Americanamafia's Avatar
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672 Posts
 Posted 04/08/2010  11:34 am  Show Profile   Bookmark this reply Add Americanamafia to your friends list Get a Link to this Reply
if you are working with titanium stock, you shouldnt have a problem because of both metals relative inertness. If it is cheap stock... you might have a problem. However the other members previous posts are not wrong, two adjacent metals will react.. if given enough time... copper is more reactive than titainum (you dont hear of copper dissolving silver coins do you lol). So without getting out my refrence books I would say your coins would be safe in titanium stock, for 1000K+ years before noticible damage. The O2 in the air will toast your coins before the titanium would! I say go for it! post some pics, sure the titanium will total your coins in a few thousand years... but so will plastic!... that said this only applies if you have quality stock!


Source: I'm a chemist!
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exodus125's Avatar
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 Posted 04/08/2010  11:43 am  Show Profile   Bookmark this reply Add exodus125 to your friends list Get a Link to this Reply
American Mafaia, good info and good point, I guess air would be far more harmful, and these tubes would be air tight.
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exodus125's Avatar
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 Posted 04/08/2010  12:01 pm  Show Profile   Bookmark this reply Add exodus125 to your friends list Get a Link to this Reply
I will have to make a wider one, the ones I have now could only carry pennies and dimes. I'm going to stick some dimes in one and see what happens after a few weeks
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Jaobler's Avatar
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 Posted 04/08/2010  3:21 pm  Show Profile   Bookmark this reply Add Jaobler to your friends list Get a Link to this Reply
Interesting discussion.

Titanium is actually a pretty "reactive" metal, in the sense that it combines with oxygen and gives off a lot of heat in the process. Finely-divided titanium is an excellent ingredient for fireworks, producing a dazzling white flame when ignited. Mix the powdered metal with some potassium nitrate or potassium chlorate and you'll be amazed how well it burns. If you are involved with machining the metal I'm sure you are aware that the shavings present a serious fire hazard.

Nevertheless, fabricated titanium pieces (like your tubes) are extremely corrosion-resistant, because the metal forms a protective layer of surface oxide that prevents any further oxidation. Among other uses, titanium is great for boat fittings because it resists saltwater corrosion better than aluminum, brass, and even stainless steel. The solid metal will have no tendency to react with silver.

Bottom line: your coins should be chemically safe in those tubes. I'd be more worried that the hard titanium metal will produce contact marks if the coins get banged into the tube. Plastic is a safer choice from that perspective.
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nod2003's Avatar
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3294 Posts
 Posted 04/08/2010  5:01 pm  Show Profile   Bookmark this reply Add nod2003 to your friends list Get a Link to this Reply
Yeah, titanium poweder does burn very nicely, but large chunks of it are extremely heat resistant. They use them in the afterburners of F-16 aircraft. You know, where those 8 foot flames come out? I think it would cost a fair amount each tube, but if you want to store your roll in style...
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exodus125's Avatar
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142 Posts
 Posted 04/11/2010  12:26 pm  Show Profile   Bookmark this reply Add exodus125 to your friends list Get a Link to this Reply
check it out. Some money shots...

I use these to store batteries and as survival tubes to store matches or a fishing kit, but the dimes fit in them nicely.

The colors on the tube are made with a very hot torch. The colors you see are caused by an oxidized layer that forms when the titanium reacts to heat and oxygen. This forms a clear layer that has the same effect as the colors you see through a bubble in the sun.

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Jaobler's Avatar
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 Posted 04/11/2010  12:37 pm  Show Profile   Bookmark this reply Add Jaobler to your friends list Get a Link to this Reply
That is a really cool storage container, and beautifully made. I expect the cost of the tube exceeds the value of the silver dimes!

I presume when you put batteries in this tube the terminals don't both touch the ends of the tube at the same time. If they did, you'd have flat batteries in short order!
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