@ijn1944: "The '76 S proof cent is copper, not plated copper/zinc. Some form of environmental agent caused the 'toning' on the coin's surface. Those cases are not airtight. Would appear that something circular 'masked' a portion of the coin in question. One can find all forms of oddities in mint sets. Kinda cool." Thanks for the feedback. So possible Coin damaged by mint packaging sealer. The back of coin looks normal, not sure what the exposed silver color is that is mostly noted in the high areas of the coins front - even more noticeable in the last right third that is missing the high gloss copper. No damage noted to the other coins, no signs that the case has been opened. Kind of odd the reverse is normal and appears like a normal proof coin. I checked the other coins in the set and found no abnormalities.