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Pre-1933 Gold XRF Test Results With Ag ?

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lib9995's Avatar
Australia
45 Posts
 Posted 02/21/2025  11:13 pm Show Profile   Bookmark this topic Add lib9995 to your friends list Get a Link to this Message Number of Subscribers
Hi guys!
I have a question about some xrf results , regarding the metal composition?
I tested 3 coins , a 1888 $1 lib, 1913 $2.50 Indian and a 1904 $20 Liberty.

I know it's supposed to be 90% Au 10% Cu , but all 3 came back with 0.3% silver? I also tested another $5 1909-d indian and that has 0.2% Silver?

They all weigh correctly and correct dimensions

I'm wondering if this is normal and has anyone else that xrf checks their coins had similar results?

I've added the pics ,
If anybody would know it's you guys!
Much appreciated &
Pre-1933-Gold-XRF-Test-Results-With-Ag-?
Pre-1933-Gold-XRF-Test-Results-With-Ag-?
Pre-1933-Gold-XRF-Test-Results-With-Ag-?
Pre-1933-Gold-XRF-Test-Results-With-Ag-?
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lib9995's Avatar
Australia
45 Posts
 Posted 02/21/2025  11:15 pm  Show Profile   Bookmark this reply Add lib9995 to your friends list Get a Link to this Reply

Pre-1933-Gold-XRF-Test-Results-With-Ag-?
Pre-1933-Gold-XRF-Test-Results-With-Ag-?
Pre-1933-Gold-XRF-Test-Results-With-Ag-?
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MisterT's Avatar
United States
2003 Posts
 Posted 02/22/2025  05:20 am  Show Profile   Bookmark this reply Add MisterT to your friends list Get a Link to this Reply
Sorry I can't help you mate, I don't have any experience with the XRF but those are some beautiful gold coins. Congrats!
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nss-52's Avatar
United States
54280 Posts
 Posted 02/22/2025  06:46 am  Show Profile   Check nss-52's eBay Listings Bookmark this reply Add nss-52 to your friends list Get a Link to this Reply
It is normal.
Show your financial support of the Coin Community Family (click here)
See my topic on Mexican Numismatic Medals (click here)
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DOCC's Avatar
United States
1502 Posts
 Posted 02/22/2025  08:00 am  Show Profile   Bookmark this reply Add DOCC to your friends list Get a Link to this Reply
Trace elements - absolutely normal.
I swing a metal detector and have a knack for finding dirty old coins.
Dirt coin restoration projects - https://www.prodetecting.com/restorations
Dirt coin restoration blog - https://www.prodetecting.com/blog/ccaw
Dirt coin dig videos - https://www.youtube.com/@prodetecting
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BStrauss3's Avatar
United States
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 Posted 02/22/2025  12:11 pm  Show Profile   Bookmark this reply Add BStrauss3 to your friends list Get a Link to this Reply
You are wrong about the composition.

https://maint.loc.gov/law/help/stat...2s3ch131.pdf


Quote:
SEC. 13. That the standard for both gold and silver coins of the United States shall be such that of one thousand parts by weight nine hundred shall be of pure metal and one hundred of alloy; and the alloy of the silver coins shall be of copper, and the alloy of the gold coins shall be of copper, or of copper and silver; but the silver shall in no case exceed one-tenth of the whole alloy.


This allows 0%-10% silver, which implies 10%-0% copper as the other 90% must be gold.
-----Burton
50+ year / Life / Emeritus ANA member (joined 12/1/1973)
Life member: Numismatics International, CONECA
Member: TNA, FtWCC, NETCC, EveryCountry (online) coin club
Owned by three cats and a wife of 40+ years (joined 1983)

Author: 3rd Edition of the Sample Slabs book, https://www.sampleslabs.info/
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United States
2281 Posts
 Posted 02/22/2025  1:58 pm  Show Profile   Bookmark this reply Add NumismaticsFTW to your friends list Get a Link to this Reply
.3 is so negligible, nothing to worry about.
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thq's Avatar
United States
3343 Posts
 Posted 02/22/2025  4:21 pm  Show Profile   Bookmark this reply Add thq to your friends list Get a Link to this Reply
UK sovereigns and French 20Fs also use copper as the secondary metal with the gold.

English guineas used an equal mixture of silver and copper for the alloy, according to this 1776 report:

The English Standard for gold is 22. carats of fine gold + 2. carats alloy. I.e. 1/12 alloy of silver and copper in equal parts.

https://founders.archives.gov/docum...1-01-02-0214

"Two minutes ago I would have sold my chances for a tired dime." Fred Astaire
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BStrauss3's Avatar
United States
4589 Posts
 Posted 02/22/2025  7:38 pm  Show Profile   Bookmark this reply Add BStrauss3 to your friends list Get a Link to this Reply
In fact, you can sometimes estimate where the silver was mined by the trace elements...

https://www.pnas.org/doi/10.1073/pnas.1018210108
https://www.sciencedirect.com/scien...409X16305107

-----Burton
50+ year / Life / Emeritus ANA member (joined 12/1/1973)
Life member: Numismatics International, CONECA
Member: TNA, FtWCC, NETCC, EveryCountry (online) coin club
Owned by three cats and a wife of 40+ years (joined 1983)

Author: 3rd Edition of the Sample Slabs book, https://www.sampleslabs.info/
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Jaobler's Avatar
United States
6381 Posts
 Posted 02/28/2025  8:12 pm  Show Profile   Bookmark this reply Add Jaobler to your friends list Get a Link to this Reply
I think I read somewhere that native California gold typically contained over 90% gold, mixed with silver and copper. Each batch of gold used for coinage would be adjusted down to 90% fineness by adding copper. The resulting coins would all have correct gold content plus variable levels of silver and copper.
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BH1964's Avatar
United States
10982 Posts
 Posted 02/28/2025  8:29 pm  Show Profile   Check BH1964's eBay Listings Bookmark this reply Add BH1964 to your friends list Get a Link to this Reply
Completely normal. BStrauss3 makes a strong point above.
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lib9995's Avatar
Australia
45 Posts
 Posted 07/04/2025  02:40 am  Show Profile   Bookmark this reply Add lib9995 to your friends list Get a Link to this Reply
have any other members had similar results? I think the better xrf machines can detect the more minute percentages too
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Portugal
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 Posted 07/08/2025  6:57 pm  Show Profile   Bookmark this reply Add jecz79 to your friends list Get a Link to this Reply
89.4 Au in a double eagle is a deviation I would not expect. Modern mints use to be very precise in gold content. But the coin certainly seems genuine. I can believe it is within the error of the machine.
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lib9995's Avatar
Australia
45 Posts
 Posted 07/11/2025  7:56 pm  Show Profile   Bookmark this reply Add lib9995 to your friends list Get a Link to this Reply
i found a shop that has a "cheaper generic brand " XRF machine and this is the results for the double eagle,,,,its not detecting any silver at all unlike the Thermo Fisher Scientific xrf machine that shows 0.3% Ag.
mmm interesting

maybe the Thermo Fisher Scientific XRF is more powerful and can detect the smaller trace elements or the generic chinese XRF is just calibrated better or somthing? for my curioisity I'm going to get all my coins tested with the generic XRF and see how they go :)
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BStrauss3's Avatar
United States
4589 Posts
 Posted 07/12/2025  08:54 am  Show Profile   Bookmark this reply Add BStrauss3 to your friends list Get a Link to this Reply
There is a highly technical thread ATS, "The Coloration Of Charlotte and Dahlonega Gold" (since we are not allowed to post links to that site).

The paper being referenced is here: https://www.researchgate.net/public..._gold_alloys
-----Burton
50+ year / Life / Emeritus ANA member (joined 12/1/1973)
Life member: Numismatics International, CONECA
Member: TNA, FtWCC, NETCC, EveryCountry (online) coin club
Owned by three cats and a wife of 40+ years (joined 1983)

Author: 3rd Edition of the Sample Slabs book, https://www.sampleslabs.info/
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lib9995's Avatar
Australia
45 Posts
 Posted 07/13/2025  05:31 am  Show Profile   Bookmark this reply Add lib9995 to your friends list Get a Link to this Reply
that was a very interesting read! cheers for that Bstrauss
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