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Acetone Experiment - Fail

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kbbpll's Avatar
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 Posted 02/02/2019  12:03 am Show Profile   Bookmark this topic Add kbbpll to your friends list Get a Link to this Message Number of Subscribers
I haven't attempted to "clean" a coin since I was 13 years old, and that was a while ago. But I've read so much about acetone on this forum that I thought I'd try it on a "junk" coin. Following the strategy laid out in several videos, I gingerly soaked for 30-60 seconds, then gently rolled (not wiped!) cotton swabs across. Nothing. So I soaked again for a couple minutes, then not quite so gently "rolled" some swabs, lathering on the acetone each time. Nothing. Then I left it in the acetone overnight, probably 20 hours or so, then aggressively went at it with the Q-tips. Before and after images. Note the unchanged blob to the right of Liberty's nose, for example. It's practically three-dimensional, and this stuff must be asphalt from getting run over by a Model-T, or some kind of impervious extraterrestrial life form. Bottom line I guess is don't expect miracles from acetone.
(white/gray color difference is lighting not coin)
Acetone-Experiment---Fail
Acetone-Experiment---Fail
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Alpha2814's Avatar
United States
2023 Posts
 Posted 02/02/2019  12:20 am  Show Profile   Bookmark this reply Add Alpha2814 to your friends list Get a Link to this Reply
Yeah, acetone isn't a cure-all. I wouldn't be so aggressive with the swabs and a longer soak can't hurt, but some things it can't help. The first couple of rounds you did would be okay in some cases, like removing gunk -- which is kinda what you have, just the wrong kind of gunk.
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MikeF's Avatar
United States
3479 Posts
 Posted 02/02/2019  12:27 am  Show Profile   Bookmark this reply Add MikeF to your friends list Get a Link to this Reply
Try hot water. I know it sounds stupid but after soaking a coin in acetone with no results, I soaked it again with hot tap water and gunk came right off. I posted the before and after here somewhere if someone wants to dig It out. I believe it was a with a Franklin half.
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kbbpll's Avatar
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 Posted 02/02/2019  12:43 am  Show Profile   Bookmark this reply Add kbbpll to your friends list Get a Link to this Reply
MikeF - interesting, I'll try that.
Hopefully it's obvious that I don't really care about whether I succeed or not with this particular coin, just thought it was a good one to experiment on.
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jimbucks's Avatar
United States
4691 Posts
 Posted 02/02/2019  12:51 am  Show Profile   Bookmark this reply Add jimbucks to your friends list Get a Link to this Reply
If it is terminal toning, basically corrosion that has eaten into the coin, then acetone won't work. On a coin like this, no reason not to dip it to complete your experiment.

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sel_69l's Avatar
Australia
21786 Posts
 Posted 02/02/2019  01:43 am  Show Profile   Bookmark this reply Add sel_69l to your friends list Get a Link to this Reply
Acetone is a powerful organic solvent. It will not dissolve metals or their oxides or sulfides which are INorganic.

Any black or or gray gunk on a coin which is not removed by acetone is almost certainly a sulfide or an oxide.
That is why it is perfectly safe to remove purely organic stains from a coin, without disturbing the patina, or the metal underneath it.
It also explains why acetone is unable to remove the black stains seen on the OP's Barber dime.


The black stains can be removed, but you need the skills of a museum professional, who do this sort of task, but almost always on ancient coins recovered from direct soil contact burial.
Acid in various dilutions are used, and that is why the skills and experience of a museum professional are essential for this job. Even so, calculated risks must be taken, because some disasters inevitably happen.

Don't ever attempt to use acid on a similar coin to the OP's. Almost 100% chance of destroying it.
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T-BOP's Avatar
United States
18456 Posts
 Posted 02/02/2019  08:48 am  Show Profile   Bookmark this reply Add T-BOP to your friends list Get a Link to this Reply
Your coin has an obvious attempt of a Harsh cleaning . Those black spots are the remaining issues after that rough cleaning ,so seems about right that the acetone will not do anything beneficial to that coin .
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kanga's Avatar
United States
5825 Posts
 Posted 02/02/2019  08:51 am  Show Profile   Bookmark this reply Add kanga to your friends list Get a Link to this Reply

Quote:
Any black or or gray gunk on a coin which is not removed by acetone is almost certainly a sulfide or an oxide.
That is why it is perfectly safe to remove purely organic stains from a coin, without disturbing the patina, or the metal underneath it.
It also explains why acetone is unable to remove the black stains seen on the OP's Barber dime.

Well said.
Acetone only deals with gunk, goo, glue, etc.
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edweather's Avatar
United States
7375 Posts
 Posted 02/02/2019  09:15 am  Show Profile   Bookmark this reply Add edweather to your friends list Get a Link to this Reply
The black stuff might be some kind of environmental damage. As long as you're pulling out the stops with nothing to lose in this experiment....do you have a pressure washer?
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cipster's Avatar
United States
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 Posted 02/02/2019  09:22 am  Show Profile   Bookmark this reply Add cipster to your friends list Get a Link to this Reply
Since you are 'experimenting' I'd suggest that in addition to acetone you might try xylene. Both are organic solvents but they can remove different junk from the coin. Acetone is a polar, organic solvent. It works differently from xylene which is non-polar. I'm not a chemist but have learned that fact from the chemists in this forum.

When I try acetone and it doesn't remove all the junk then I try xylene and sometimes it removes it because polar dissolves polar junk and non-polar dissolves non-polar junk.
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"You got to lose to know how to win".
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mcshilling's Avatar
Canada
9155 Posts
 Posted 02/02/2019  09:41 am  Show Profile   Bookmark this reply Add mcshilling to your friends list Get a Link to this Reply
After acetone I use Verdi-care
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jafo50's Avatar
United States
175 Posts
 Posted 02/02/2019  09:54 am  Show Profile   Bookmark this reply Add jafo50 to your friends list Get a Link to this Reply
If you do try xylene make sure there's plenty of ventilation. It's some nasty stuff.
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 Posted 02/02/2019  09:54 am  Show Profile   Bookmark this reply Add just carl to your friends list Get a Link to this Reply
Usually if Acetone doesn't work, distilled water too has no effect, the coin may be really in sad shape. Might not be worth saving after all that.
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Spence's Avatar
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34397 Posts
 Posted 02/02/2019  10:35 am  Show Profile   Bookmark this reply Add Spence to your friends list Get a Link to this Reply
When in doubt, you could consult the wise words of @bad thad:


http://goccf.com/t/324115&whichpage=2#2763607
"If you climb a good tree, you get a push."
-----Ghanaian proverb

"The danger we all now face is distinguishing between what is authentic and what is performed."
-----King Adz
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kbbpll's Avatar
United States
4233 Posts
 Posted 02/02/2019  1:56 pm  Show Profile   Bookmark this reply Add kbbpll to your friends list Get a Link to this Reply
You guys missed the obvious solution - just spray paint it silver. :)
Under the microscope it all seems like a permanent part of the metal now, whatever it is. So I'm moving on. The coin I really care about under the scope has some green plastic looking nodules embedded in various places, thinking leftover PVC gunk, so I might still try acetone on that. Thanks for all the suggestions.
Acetone-Experiment---Fail
Acetone-Experiment---Fail
Acetone-Experiment---Fail
Acetone-Experiment---Fail
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edweather's Avatar
United States
7375 Posts
 Posted 02/02/2019  5:34 pm  Show Profile   Bookmark this reply Add edweather to your friends list Get a Link to this Reply
Nice pics though.
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