The ancient Romans were the first to use something resembling a decimal system, though it was largely by accident rather than an intent to "go decimal".
The basic Roman monetary unit was the copper "as". In the Early Imperial period, there were four asses to the sestertius (which was the money of account), four sestertii to the denarius, and 25 denarii to the gold aureus. Thus, an aureus was worth 100 sestertii. This ratio remained in place until the value of the denarius collapsed in the mid-200s AD.
In the earlier Republic period, the denarius was originally worth 10 asses - its name literally means "worth 10 asses", and early denarii bore the denomination-mark "X" for 10. In 141 BC, the face value was increased to 16 asses, though the name remained the same.
Don't forget, people back then didn't have a base-10 numeral system (1, 2, 3, etc). Mathematics had to be done using Roman numerals, which was cumbersome - so it didn't really matter whether the currency was in base 10 or not, the maths would be just as hard.
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Other than that, though, yeah, pretty much. AFAIK the USA, in 1792 (or so), was actually the first of the main wave of decimalization.
The Americans may have been the first (apart from the Russians), but it was the French coming second, in 1795, that decimalized the world.
Revolutionary France decimalized everything - all units of distance, weight and even time (though the decimal clock and decimal calendar never really took off). It was all part of the revolutionary doctrine, of throwing out the old and replacing it with the new. Money was just one small part of the decimalization craze.
And it is the French you can thank for forcing the rest of Europe to go decimal; when France conquered most of Europe, they enforced the French standards of weights, including money. Most of the places France conquered never bothered re-instating their old currencies and units of measure after they regained independence. And guess which piece of Europe was never conquered by revolutionary France? That's right, Britain - the only non-Metric, non-Decimal holdout.
As for why America adopted decimal currency, it was partly for alignment with Revolutionary France, and partly for the same reason the French found: throwing out the old symbols of the old regime. Unlike weights and distance, the revolutionary Americans
had to get rid of the old British currency, because it was covered in Royalist symbolism. And if you're going to go to all the trouble of replacing all the coins, you might as well reform the currency to something more logical while you're at it.
That it wasn't really a matter of mathematical convenience or necessity that drove the decision, can be seen in the continuation of the non-metric fraction of the quarter-dollar. Quarter-dollars were already in circulation, thanks to the prevalence of Spanish colonial coins in trade. The belated attempt to replace the quarter with a 20 cent piece in the 1870s was too little, too late. The American currency system remains on a quasi-decimal basis as a result.
Don't say "infinitely" when you mean "very"; otherwise, you'll have no word left when you want to talk about something really infinite. - C. S. Lewis